Aerosol optical properties calculated from size distributions, filter samples and absorption photometer data at Dome C, Antarctica, and their relationships with seasonal cycles of sources

• Published in: Atmospheric chemistry and physics 2022-04, Vol.22 (7), p.5033-5069
• Main Authors: Virkkula, Aki, Grythe, Henrik, Backman, John, Petäjä, Tuukka, Busetto, Maurizio, Lanconelli, Christian, Lupi, Angelo, Becagli, Silvia, Traversi, Rita, Severi, Mirko, Vitale, Vito, Sheridan, Patrick, Andrews, Elisabeth
• Format: Article
• Language: English
• Subjects: Absorption; Absorption coefficient; Absorptivity; Aerosol optical properties; Aerosols; Air masses; Albedo; Albedo (solar); Algorithms; Altitude; Biomass; Biomass burning; Black carbon; Burning; Coefficients; Comparative analysis; Cycles; Domes; Emission measurements; Emissions; Humidity; Lidar; Marine aerosols; Mathematical analysis; Monthly; Nephelometers; Optical instruments; Optical properties; Optical radar; Photometers; Phytoplankton; Plumes; Polar regions; Scattering coefficient; Sea level; Seasonal variation; Secondary aerosols; Smoke plumes; Soot; South Pole; Spray; Summer; Wavelength; Wildfires; Winter
• ISSN: 1680-7324; 1680-7316; 1680-7324
• DOI: 10.5194/acp-22-5033-2022

Optical properties of surface aerosols at Dome C, Antarctica, in 2007–2013 and their potential source areas are presented. Scattering coefficients (σsp) were calculated from measured particle number size distributions with a Mie code and from filter samples using mass scattering efficiencies. Absorption coefficients (σap) were determined with a three-wavelength Particle Soot Absorption Photometer (PSAP) and corrected for scattering by using two different algorithms. The scattering coefficients were also compared with σsp measured with a nephelometer at the South Pole Station (SPO). The minimum σap was observed in the austral autumn and the maximum in the austral spring, similar to other Antarctic sites. The darkest aerosol, i.e., the lowest single-scattering albedo ωo≈0.91, was observed in September and October and the highest ωo≈0.99 in February and March. The uncertainty of the absorption Ångström exponent αap is high. The lowest αap monthly medians were observed in March and the highest in August–October. The equivalent black carbon (eBC) mass concentrations were compared with eBC measured at three other Antarctic sites: the SPO and two coastal sites, Neumayer and Syowa. The maximum monthly median eBC concentrations are almost the same (∼3±1 ng m−3) at all these sites in October–November. This suggests that there is no significant difference in eBC concentrations between the coastal and plateau sites. The seasonal cycle of the eBC mass fraction exhibits a minimum f(eBC) ≈0.1 % in February–March and a maximum ∼4 %–5 % in August–October. Source areas were calculated using 50 d FLEXPART footprints. The highest eBC concentrations and the lowest ωo were associated with air masses coming from South America, Australia and Africa. Vertical simulations that take BC particle removal processes into account show that there would be essentially no BC particles arriving at Dome C from north of latitude 10∘ S at altitudes