Kinetic Study of the Catalytic Pyrolysis of Oil-Containing Waste

Basing on the experimental data the optimal parameters of the pyrolysis of heavy and residual hydrocarbons of oil were defined as follows: temperature of 500 °С; catalyst  of CoCl2 with the catalyst loading 5% (wt.) of the substrate weight. Under the optimal conditions the kinetic investigation of t...

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Bibliographic Details
Published in:Bulletin of chemical reaction engineering & catalysis 2016-01, Vol.11 (3), p.330-338
Main Authors: Chalov, Kirill, Lugovoy, Yury, Kosivtsov, Yury, Sulman, Mikhail, Sulman, Esther, Valentina Matveeva, Valentina Matveeva, Stepacheva, Antonina
Format: Article
Language:English
Subjects:
Catalysts
heavy and residual hydrocarbons
kinetic
metals chlorides
Pyrolysis
thermocatalytic processing
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Summary:Basing on the experimental data the optimal parameters of the pyrolysis of heavy and residual hydrocarbons of oil were defined as follows: temperature of 500 °С; catalyst  of CoCl2 with the catalyst loading 5% (wt.) of the substrate weight. Under the optimal conditions the kinetic investigation of the pyrolysis process was carried out using the thermogravimetric method. According to the investigation, it was found that the activation energy of the catalytic pyrolysis of oil-containing waste decreased by 20-30 kJ/mol in comparison to non-catalytic process. 
ISSN:1978-2993
1978-2993
DOI:10.9767/bcrec.11.3.572.330-338