Di-μ-chlorido-dichloridobis{8-[2-(dimethylamino)ethylamino]quinoline}dicadmium monohydrate

The title complex, [Cd2Cl4(C13H17N3)2]·H2O, is centrosymmetic and contains two Cd2+ ions bridged by two Cl− ions, leading to a strictly planar Cd2Cl2 core. Each Cd2+ ion is further coordinated by an additional Cl− ion and three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-09, Vol.69 (9), p.m491-m492
Main Authors: Al-Sudani, Abdul-Razak H., Kariuki, Benson M.
Format: Article
Language:English
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Summary:The title complex, [Cd2Cl4(C13H17N3)2]·H2O, is centrosymmetic and contains two Cd2+ ions bridged by two Cl− ions, leading to a strictly planar Cd2Cl2 core. Each Cd2+ ion is further coordinated by an additional Cl− ion and three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand in the form of a considerably distorted octahedron for the overall coordination sphere. A lattice water molecule is located on a twofold rotation axis and links pairs of complexes through N-H...O and O-H...Cl hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053681302206X