Azido-(benzoyl-acetonato-κO,O')[1-phenyl-3-(2-pyridylmethyl-imino)but-1-en-1-olato-κN,N',O]cobalt(III)

In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate liga...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-02, Vol.66 (Pt 3), p.m248-m248
Main Authors: Datta, Amitabha, Sie, Ming-Han, Huang, Jui-Hsien, Lee, Hon Man
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular C(ar-yl)-H⋯O hydrogen bonds are present in the structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810003338