ELECTROCHEMICAL STUDIES IN THE SYNTHESIS OF N-F COMPOUNDS

This report describes work which has been devoted to the development of a suitable working electrode for use in electrochemical fluorination studies in anhydrous HF (AHF). Investigations of possible working electrodes have involved antimony, bismuth, silver, aluminum, titanium, cobalt, iron, and mon...

Full description

Saved in:
Bibliographic Details
Main Authors: Spears, Larry G, Fiel, Larry D, Harrell, Jr , Wallace E, Schmid, Gerhard M
Format: Report
Language:English
Subjects:
ALUMINUM
AMMONIA
AMMONIUM COMPOUNDS
ANODES(ELECTROLYTIC CELL)
ANTIMONY
BISMUTH
COBALT
COPPER
CORROSION
Electrochemical Energy Storage
ELECTROCHEMISTRY
ELECTRODES
FLUORIDES
FLUORINATION
FLUORINE COMPOUNDS
HALOCARBON PLASTICS
HYDRAZINES
HYDROGEN
HYDROGEN COMPOUNDS
Inorganic Chemistry
IRON
MATERIALS
METALS
MONEL METAL
NICKEL ALLOYS
NITROGEN COMPOUNDS
POLARIZATION
SILVER
SYNTHESIS(CHEMISTRY)
Online Access:Request full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:This report describes work which has been devoted to the development of a suitable working electrode for use in electrochemical fluorination studies in anhydrous HF (AHF). Investigations of possible working electrodes have involved antimony, bismuth, silver, aluminum, titanium, cobalt, iron, and monel. Antimony, bismuth, and silver show a high anodic dissolution rate in AHF, while the other metals studied show passive behavior. Of the latter metals only monel formed a protective coating which permitted appreciable fluorine evolution to occur.