NEW IRON-CONTAINING MONOMERS AND POLYMERS FROM FIVE-MEMBERED NAPHTHENES

The alkylation of ferrocene by different olefins (iso- C4H8, iso-C5H10, and iso-C8H16) in the presence of 25% H3PO4 is described. BF3 at the optimum conditions of 60C and a 5-hr. agitation period, is compared. With an increase in olefin molecular weight, there is a decrease in alkylate yield and fer...

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Bibliographic Details
Main Authors: Paushkin,Ya M, Vishnyakova,T P, Sokolinskaya,T A, Patalakh,I I, Machus,F F
Format: Report
Language:English
Subjects:
ALKYLATION
CHEMICAL PROPERTIES
CONDENSATION REACTIONS
FERROCENES
INFRARED SPECTRA
METALORGANIC POLYMERS
MOLECULAR ORBITALS
MOLECULAR STRUCTURE
ORGANOMETALLIC COMPOUNDS
PARAMAGNETIC RESONANCE
PHYSICAL PROPERTIES
Polymer Chemistry
POLYMERIZATION
POLYMERS
TRANSLATIONS
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Summary:The alkylation of ferrocene by different olefins (iso- C4H8, iso-C5H10, and iso-C8H16) in the presence of 25% H3PO4 is described. BF3 at the optimum conditions of 60C and a 5-hr. agitation period, is compared. With an increase in olefin molecular weight, there is a decrease in alkylate yield and ferrocene conversion accompanied by an increase of monoalkylferrocene content. The physical-chemical properties of the prepared alkylferrocenes are listed. Ferrocene and alkylferrocene were then used to obtain ferrocenyl-containing polymers by the polyrecombination reaction which consists of peroxide treatment at 170-200C. The joint polyrecombination of ferrocene with paradichlorobenzene, diphenol, alpha-bromonaphthalene and quinoline was also investigated and the data are tabulated. Soluble polymers were obtained by the polycondensation of ferrocene with acetone in the presence of ZnCl2 + HCl. The preparation of polyferrocenylvinylene from acetylferrocene is described. (Author) Edited trans. of Institut Neftekhmicheskoi i Gazovoi Promyshlennosti, Moscow. Trudy (USSR) n44 p15-26 1963, tr. by H. Peck.