COMPLEXES OF B9H10CHP(-) AND B9H10CHAs(-) WITH GROUP VI METAL CARBONYLS

The photochemical reaction of (CH3)4N(B9H10CHE) (E = P or As) with group VI metal carbonyls lead to the formation of complexes of the general formula, (CH3)4N(B9H10CHEM(CO)5). Available evidence suggests that the phosphorus or arsenic atom of the ligand is sigma bonded to the metal carbonyl in these...

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Bibliographic Details
Main Authors: Todd,Lee J, Silverstein,Howard T, Beer,Don C
Format: Report
Language:English
Subjects:
ARSENIC COMPOUNDS
BORANES
CHEMICAL BONDS
CHROMIUM CARBONYLS
CHROMIUM COMPOUNDS
COMPLEX COMPOUNDS
DODECABORANE/1-2-DICARBACLOSO
DODECABORANES
GROUP 6 ELEMENTS
Inorganic Chemistry
IONS
IRON CARBONYLS
IRON COMPOUNDS
METAL CARBONYLS
MOLYBDENUM CARBONYLS
MOLYBDENUM COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
Organic Chemistry
ORGANOMETALLIC COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOTOCHEMICAL REACTIONS
SYNTHESIS(CHEMISTRY)
TUNGSTEN CARBONYLS
TUNGSTEN COMPOUNDS
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Summary:The photochemical reaction of (CH3)4N(B9H10CHE) (E = P or As) with group VI metal carbonyls lead to the formation of complexes of the general formula, (CH3)4N(B9H10CHEM(CO)5). Available evidence suggests that the phosphorus or arsenic atom of the ligand is sigma bonded to the metal carbonyl in these new derivatives. (Author)