The Urethane-Alcohol Reaction

The formation of polyurethanes from blocked isocyanates involves a transesterification reaction, the mechanism(s) of which is not well understood. A model of this transesterification reactions, namely the reaction of aryl carbanilates with alcohols was studied.

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Bibliographic Details
Main Author: Rand,Leon
Format: Report
Language:English
Subjects:
ALCOHOLS
CHEMICAL REACTION MECHANISMS
CHEMICAL REACTIONS
ESTERIFICATION
ISOCYANATES
Organic Chemistry
Plastics
REACTION KINETICS
SYNTHESIS(CHEMISTRY)
URETHANE
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Description
Summary:The formation of polyurethanes from blocked isocyanates involves a transesterification reaction, the mechanism(s) of which is not well understood. A model of this transesterification reactions, namely the reaction of aryl carbanilates with alcohols was studied.