Optical Interference Phenomenon

Experimental measurements of the formation of vibrationally excited ozone resulting from O + O2 + M to O3(*) + M, M = O2, N2 are reported. The bulk rate constant and the exothermicity of the reaction going into various vibrational states of ozone are given. The rate for vibrational relaxation O3(*)...

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Bibliographic Details
Main Authors: VON Rosenberg, Jr , C W, Trainor, Daniel W, Lowenstein, Andrew
Format: Report
Language:English
Subjects:
Atmospheric Physics
Atom molecule interactions
Atomic and Molecular Physics and Spectroscopy
CARBON DIOXIDE
CARBON DIOXIDE LASERS
ENERGY TRANSFER
EXCITATION
Molecular relaxation
MOLECULAR VIBRATION
OZONE
RATES
REACTION KINETICS
Recombination reactions
RELAXATION
SORPTION
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Summary:Experimental measurements of the formation of vibrationally excited ozone resulting from O + O2 + M to O3(*) + M, M = O2, N2 are reported. The bulk rate constant and the exothermicity of the reaction going into various vibrational states of ozone are given. The rate for vibrational relaxation O3(*) + M to O3 + M was also measured. Separate experiments on the absorption of CO2 9.6 micrometer laser lines by ozone are described as well as a measurement of CO2 relaxation by ozone.