Synthesis and Properties of Selected Energetic Organodi- and Polyammonium Nitrate Salts

The objective of this program was to synthesize and characterize selected organodi- and polyammonium nitrate salts for use in a qualitative study of thermal and impact stability characteristics. A total of twenty-two salts were prepared and characterized. A literature search confirmed that fifteen o...

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Bibliographic Details
Main Authors: Hildreth, Robert A, Fryling, James A, Struck, Stephen R, McKenney, Robert L , Jr
Format: Report
Language:English
Subjects:
AMMONIUM NITRATE
Ammunition and Explosives
DENSITY
DIAMMONIUM NITRATE SALTS
ENERGETIC NITRATE SALTS
EQUATIONS
EXOTHERMIC DECOMPOSITION
EXPLOSIVES
FY86
HEAT OF FUSION
IMPACT STABILITY
Industrial Chemistry and Chemical Processing
Inorganic Chemistry
INORGANIC COMPOUNDS
LITERATURE SURVEYS
MELTING POINT
NMR(NUCLEAR MAGNETIC RESONANCE)
Organic Chemistry
ORGANIC COMPOUNDS
PE62602F
POLYAMMONIUM NITRATE SALTS
QUALITATIVE ANALYSIS
SENSITIVITY
SYNTHESIS(CHEMISTRY)
TEMPERATURE
THERMAL STABILITY
WUAFATL25021012
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Description
Summary:The objective of this program was to synthesize and characterize selected organodi- and polyammonium nitrate salts for use in a qualitative study of thermal and impact stability characteristics. A total of twenty-two salts were prepared and characterized. A literature search confirmed that fifteen of these materials had never been reported and, therefore, were assumed to be original. The general synthetic process is described with specific details for each compound included. Elemental analyses are provided for the new compounds as well as their nuclear magnetic resonance spectra. Other data included are densities (calculated and measured), heats of fusion, melting points, and the temperature of the major peak associated with exothermic decomposition as measured by a differential scanning calorimeter.