Synthesis and Characterization of Mesitylgallium Chloride Compounds Including the Crystal and Molecular Structure of Dichloromesitylgallium (III), an Inorganic Polymer

The mesitylgallium chloride compounds, GaMes2Cl and GaMesCl2, have been prepared and fully characterized by melting point data, elemental analyses, solubility properties, IR and Hydrogen 1 and Carbon 13 NMR spectroscopic data and Lewis acidity studies. Cryoscopic molecular weight studies of GaMes2Cl...

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Bibliographic Details
Main Authors: Beachley,O T , Jr, Churchill,Melvyn R, Pazik,John C, Ziller,Joseph W
Format: Report
Language:English
Subjects:
ACIDS
BENZENE
BRIDGES
CHLORIDES
CRYOGENICS
ETHYLENE OXIDE
GALLIUM COMPOUNDS
HIGH TEMPERATURE
HYDROCARBONS
Inorganic Chemistry
INORGANIC POLYMERS
LIGANDS
MELTING POINT
Mesitylgallium chloride
MOLECULAR STRUCTURE
MOLECULAR WEIGHT
ONE DIMENSIONAL
Polymer Chemistry
POLYMERS
SOLIDS
SOLUBILITY
SOLUTIONS(GENERAL)
SOLVENTS
SPECTROSCOPY
SYNTHESIS(CHEMISTRY)
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Summary:The mesitylgallium chloride compounds, GaMes2Cl and GaMesCl2, have been prepared and fully characterized by melting point data, elemental analyses, solubility properties, IR and Hydrogen 1 and Carbon 13 NMR spectroscopic data and Lewis acidity studies. Cryoscopic molecular weight studies of GaMes2Cl in benzene solution are consistent with the presence of dimeric molecules. Lewis bases such as Ethylene Oxide and Tetrahydrofuran (THF) react with (GaMes2Cl)2 in benzene to establish two equilibria which are consistent with the presence of the dimer, a monochloride bridged 2:1 adduct ((GaMes2Cl)2-base) and the 1:1 adduct. The dichloro derivative GaMesCl2 is an unusually high melting solid which is insoluble in hydrocarbon solvents and crystallizes in the centrosymmetric monoclinic space group. Dichloromesitylgallium(III) is a one-dimensional polymer in which planar Ga(mesityl)Cl units are linked by bridging chloride ligands.