Chemistry of Polynitroethane Derivatives

1,2-Difluorodinitroethylene was prepared by pyrolysis of 1,2- difluorotetranitroethane. Reactions of 1,1,-diiododinitroethylene with nucleophiles were studied. Nitrations of 1,1-diamino-2,2-dinitroethylenes gave trinitromethyl derivatives. Fluoride ion reacted with 1,1-diiododinitroethylene to give...

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Bibliographic Details
Main Author: Baum, Kurt
Format: Report
Language:English
Subjects:
2-DIFLUOROTETRANITROETHANE
Ammunition and Explosives
ANTHRACENES
BONDING
CHEMISTRY
DIELS ALDER TRAPPING EXPERIMENTS
ELECTRONEGATIVE ORGANIC SUBSTITUENTS
ENERGETIC PROPERTIES
EXPLOSIVES
FLUORIDES
IONS
NITRO RADICALS
OLEFIN POLYMERS
Organic Chemistry
Physical Chemistry
Polymer Chemistry
POLYNITROETHANE DERIVATIVES
POLYNITROOLEFINS
PROPELLANTS
PYROLYSIS
Rocket Propellants
SALTS
TETRANITROETHYLENE
THERMOLYSIS
X RAY DIFFRACTION
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Summary:1,2-Difluorodinitroethylene was prepared by pyrolysis of 1,2- difluorotetranitroethane. Reactions of 1,1,-diiododinitroethylene with nucleophiles were studied. Nitrations of 1,1-diamino-2,2-dinitroethylenes gave trinitromethyl derivatives. Fluoride ion reacted with 1,1-diiododinitroethylene to give trifluorodinitroethane salts, used to prepare 3,3,3-trifluoro-2, 2dinitropropyl formal. Thermolysis of 1,1,2-tribromotrinitroethane gave 1,2-and 1,1-dibromodinitroethylene. 1,2-Difluorodinitroethylene, 1,2- diiododinitroethylene, Dibromodinitroethylene, 3,3,3-trifluoro-2,2- dinitropropanol, trinitromethyl compounds, Crystallography.