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Single Lithium Ion Conducting Polymer Electrolyte

Because of the importance of this starting material, considerable effort was expended on modification of the reported workup. Elimination of all extraction and careful acidification of the diluted reaction mixture at low temperature leads to a consistent 40-50% yield of product exhibiting the charac...

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Main Authors: Feld, William A, Weimers, Denise M
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creator Feld, William A
Weimers, Denise M
description Because of the importance of this starting material, considerable effort was expended on modification of the reported workup. Elimination of all extraction and careful acidification of the diluted reaction mixture at low temperature leads to a consistent 40-50% yield of product exhibiting the characteristics of previously prepared samples. In addition to our interest in this material it appears to be an important starting material for the synthesis of anthracycline intermediates. Anthracyclines are used as antitumor antibiotics (c.f., Henry, D.W., Cancer. Treat. Rep 1979, 63, 845) in which they act as DNA intercalators. A publication specifying the details of the synthesis and workup is being prepared.
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Elimination of all extraction and careful acidification of the diluted reaction mixture at low temperature leads to a consistent 40-50% yield of product exhibiting the characteristics of previously prepared samples. In addition to our interest in this material it appears to be an important starting material for the synthesis of anthracycline intermediates. Anthracyclines are used as antitumor antibiotics (c.f., Henry, D.W., Cancer. Treat. Rep 1979, 63, 845) in which they act as DNA intercalators. 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source DTIC Technical Reports
subjects ANTHRACENES
ANTHRACYLINES
ANTIBIOTICS
COMPUTATIONAL CHEMISTRY
Electrochemical Energy Storage
LITHIUM BATTERIES
MODIFICATION
NAPHTHALENES
Organic Chemistry
PE61102F
Physical Chemistry
POLYELECTROLYTES
POLYMER ELECTROLYTES
PORPHYRINS
SYNTHESIS(CHEMISTRY)
WUAFOSR2303BV
title Single Lithium Ion Conducting Polymer Electrolyte
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