New cationic clathrate: synthesis and structure of [Si 40P 6]I 6.5

The [Si 40P 6]I 6.5 cationic clathrate possessing the type-I clathrate structure with a minimal known unit-cell volume and a remarkably high vacancy concentration in the guest sublattice was synthesised.

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Bibliographic Details
Published in:Mendeleev communications 2004-07, Vol.14 (4), p.135-136
Main Authors: Kovnir, Kirill A., Uglov, Alexei N., Zaikina, Julia V., Shevelkov, Andrei V.
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:The [Si 40P 6]I 6.5 cationic clathrate possessing the type-I clathrate structure with a minimal known unit-cell volume and a remarkably high vacancy concentration in the guest sublattice was synthesised.
ISSN:0959-9436
DOI:10.1070/MC2004v014n04ABEH001945