environmentally benign room temperature aqueous homo- and copolymerization of styrene and methylmethacrylate catalyzed by [Cp₂TiCl₂]/NaBPh

[Cp₂TiCl₂] has been found to be an effective precatalyst for room temperature aqueous homo- and copolymerization of methyl methacrylate and styrene in the presence of a cocatalyst, NaBPh₄ and an emulsifier, sodium n-dodecyl sulfate. The polymers obtained are of high molecular weight with low molecul...

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Bibliographic Details
Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2009, Vol.47 (23), p.6496-6503
Main Authors: De, Sudip K, Bhattacharjee, Manish
Format: Article
Language:English
Online Access:Get full text
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Summary:[Cp₂TiCl₂] has been found to be an effective precatalyst for room temperature aqueous homo- and copolymerization of methyl methacrylate and styrene in the presence of a cocatalyst, NaBPh₄ and an emulsifier, sodium n-dodecyl sulfate. The polymers obtained are of high molecular weight with low molecular weight distribution.
ISSN:0887-624X
1099-0518