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Synthesis and aminomethylation of 9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates
10-Amino-7,11-dicyano-9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates have been obtained by the interaction of N -alkylpiperidin-4-ones with 2 equiv. cyanoselenoacetamide or with malononitrile and cyanoselenoacetamide. Aminomethylation of the obtained compounds proceeded under mild condition...
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| Published in: | Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2013-06, Vol.49 (3), p.472-478 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c327t-f7c3169c916bb9624eefaaa7b674f57a2a7196bb5168915e21cca412d8765adb3 |
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| cites | cdi_FETCH-LOGICAL-c327t-f7c3169c916bb9624eefaaa7b674f57a2a7196bb5168915e21cca412d8765adb3 |
| container_end_page | 478 |
| container_issue | 3 |
| container_start_page | 472 |
| container_title | Chemistry of heterocyclic compounds (New York, N.Y. 1965) |
| container_volume | 49 |
| creator | Frolov, K. A. Dotsenko, V. V. Krivokolysko, S. G. Zubatyuk, R. I. Shishkin, O. V. |
| description | 10-Amino-7,11-dicyano-9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates have been obtained by the interaction of
N
-alkylpiperidin-4-ones with 2 equiv. cyanoselenoacetamide or with malononitrile and cyanoselenoacetamide. Aminomethylation of the obtained compounds proceeded under mild conditions and led to the formation of 8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tri-cyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-dicarbonitriles. The structure of 1-methyl-5',11'-di(4-methyl-phenyl)-8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tricyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-di-carbonitrile was determined by X-ray structural analysis. |
| doi_str_mv | 10.1007/s10593-013-1270-9 |
| format | article |
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N
-alkylpiperidin-4-ones with 2 equiv. cyanoselenoacetamide or with malononitrile and cyanoselenoacetamide. Aminomethylation of the obtained compounds proceeded under mild conditions and led to the formation of 8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tri-cyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-dicarbonitriles. The structure of 1-methyl-5',11'-di(4-methyl-phenyl)-8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tricyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-di-carbonitrile was determined by X-ray structural analysis.</description><identifier>ISSN: 0009-3122</identifier><identifier>EISSN: 1573-8353</identifier><identifier>DOI: 10.1007/s10593-013-1270-9</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Organic Chemistry ; Pharmacy ; Pyridine</subject><ispartof>Chemistry of heterocyclic compounds (New York, N.Y. 1965), 2013-06, Vol.49 (3), p.472-478</ispartof><rights>Springer Science+Business Media New York 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c327t-f7c3169c916bb9624eefaaa7b674f57a2a7196bb5168915e21cca412d8765adb3</citedby><cites>FETCH-LOGICAL-c327t-f7c3169c916bb9624eefaaa7b674f57a2a7196bb5168915e21cca412d8765adb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Frolov, K. A.</creatorcontrib><creatorcontrib>Dotsenko, V. V.</creatorcontrib><creatorcontrib>Krivokolysko, S. G.</creatorcontrib><creatorcontrib>Zubatyuk, R. I.</creatorcontrib><creatorcontrib>Shishkin, O. V.</creatorcontrib><title>Synthesis and aminomethylation of 9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates</title><title>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</title><addtitle>Chem Heterocycl Comp</addtitle><description>10-Amino-7,11-dicyano-9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates have been obtained by the interaction of
N
-alkylpiperidin-4-ones with 2 equiv. cyanoselenoacetamide or with malononitrile and cyanoselenoacetamide. Aminomethylation of the obtained compounds proceeded under mild conditions and led to the formation of 8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tri-cyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-dicarbonitriles. The structure of 1-methyl-5',11'-di(4-methyl-phenyl)-8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tricyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-di-carbonitrile was determined by X-ray structural analysis.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Organic Chemistry</subject><subject>Pharmacy</subject><subject>Pyridine</subject><issn>0009-3122</issn><issn>1573-8353</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEQgIMoWKsP4K0PYGom2Ww2xyL-QcGDehCRMM3OakqbyGZ7qE9vynqWgRlmJt9APsYuQcxBCHOdQWiruADFQRrB7RGbgDaKN0qrYzYRQliuQMpTdpbzurQGmmrC3p73cfiiHPIMYzvDbYhpS8PXfoNDSHGWupnl-INclZxiwPwd-vSur_THLrbkkZsrELwNFIk3PNOGYios5XN20uEm08VfnbLXu9uXmwe-fLp_vFksuVfSDLwzXkFtvYV6tbK1rIg6RDSr2lSdNijRgC0rDXVjQZME77EC2Tam1tiu1JTNx7ufuCEXYpeGHn2JlrbBp0hdKPOFUtaoSlW6ADACvk8599S57z5ssd87EO4g040yXZHpDjKdLYwcmVzexk_q3Trt-lj-9Q_0C9rwdqo</recordid><startdate>20130601</startdate><enddate>20130601</enddate><creator>Frolov, K. A.</creator><creator>Dotsenko, V. V.</creator><creator>Krivokolysko, S. G.</creator><creator>Zubatyuk, R. I.</creator><creator>Shishkin, O. V.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130601</creationdate><title>Synthesis and aminomethylation of 9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates</title><author>Frolov, K. A. ; Dotsenko, V. V. ; Krivokolysko, S. G. ; Zubatyuk, R. I. ; Shishkin, O. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-f7c3169c916bb9624eefaaa7b674f57a2a7196bb5168915e21cca412d8765adb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Organic Chemistry</topic><topic>Pharmacy</topic><topic>Pyridine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Frolov, K. A.</creatorcontrib><creatorcontrib>Dotsenko, V. V.</creatorcontrib><creatorcontrib>Krivokolysko, S. G.</creatorcontrib><creatorcontrib>Zubatyuk, R. I.</creatorcontrib><creatorcontrib>Shishkin, O. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Frolov, K. A.</au><au>Dotsenko, V. V.</au><au>Krivokolysko, S. G.</au><au>Zubatyuk, R. I.</au><au>Shishkin, O. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and aminomethylation of 9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates</atitle><jtitle>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</jtitle><stitle>Chem Heterocycl Comp</stitle><date>2013-06-01</date><risdate>2013</risdate><volume>49</volume><issue>3</issue><spage>472</spage><epage>478</epage><pages>472-478</pages><issn>0009-3122</issn><eissn>1573-8353</eissn><abstract>10-Amino-7,11-dicyano-9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates have been obtained by the interaction of
N
-alkylpiperidin-4-ones with 2 equiv. cyanoselenoacetamide or with malononitrile and cyanoselenoacetamide. Aminomethylation of the obtained compounds proceeded under mild conditions and led to the formation of 8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tri-cyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-dicarbonitriles. The structure of 1-methyl-5',11'-di(4-methyl-phenyl)-8'-selenoxo-3',5',7',11'-tetraazaspiro[piperidine-4,13'-tricyclo[7.3.1.0
2,7
]tridec[2]ene]-1',9'-di-carbonitrile was determined by X-ray structural analysis.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10593-013-1270-9</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0009-3122 |
| ispartof | Chemistry of heterocyclic compounds (New York, N.Y. 1965), 2013-06, Vol.49 (3), p.472-478 |
| issn | 0009-3122 1573-8353 |
| language | eng |
| recordid | cdi_gale_infotracacademiconefile_A339734345 |
| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Organic Chemistry Pharmacy Pyridine |
| title | Synthesis and aminomethylation of 9-aza-3-azoniaspiro[5,5]undeca-7,10-diene-8-selenolates |
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