Effect of the nuclearity and ligand environment of cobalt on the catalytic characteristics of its pivalate complexes on the liquid-phase oxidation of cyclohexene by oxygen

The main products from the liquid-phase oxidation of cyclohexane (CH) by air (333 K) in the presence of the pivalate complexes of cobalt with nuclearity n = 1–4 are the respective hydroperoxide (HP) and cyclohexenone. The effect of n on the rate of formation W HP (Co 1

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Bibliographic Details
Published in:Theoretical and experimental chemistry 2010-05, Vol.46 (1), p.14-19
Main Authors: Chikhichin, D. G., Kotseruba, V. A., Levchenko, O. A., Perova, E. V., Anan’ev, I. V., Nefedov, S. E., Sidorov, A. A., Eremenko, I. L., Malaeshtyan, Yu. L., Timco, G. A., Kamalov, G. L.
Format: Article
Language:English
Subjects:
Chemical properties
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Cobalt
Cyclohexane
Olefins
Oxidation-reduction reaction
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Summary:The main products from the liquid-phase oxidation of cyclohexane (CH) by air (333 K) in the presence of the pivalate complexes of cobalt with nuclearity n = 1–4 are the respective hydroperoxide (HP) and cyclohexenone. The effect of n on the rate of formation W HP (Co 1
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-010-9114-5