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Crystal structure and electrical properties of [Gd.sub.x][Mn.sub.1 - x]S and [Ti.sub.x][Mn.sub.1 - x]Se solid solutions

Regions of the existence of sulfide [Gd.sub.x][Mn.sub.1 - x]S and selenide [Ti.sub.x][Mn.sub.1 - x]Se solid solutions have been identified. Their electrical and thermoelectric properties have been studied in the temperature range 80-900 K. It has been established that the substitution of [Gd.sup.2+]...

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Published in:Physics of the solid state 2010-04, Vol.52 (4), p.687
Main Authors: Galyas, A.I, Demidenko, O.F, Makovetskii, G.I, Yanushkevich, K.I, Ryabinkina, L.I, Romanova, O.B
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container_title Physics of the solid state
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Demidenko, O.F
Makovetskii, G.I
Yanushkevich, K.I
Ryabinkina, L.I
Romanova, O.B
description Regions of the existence of sulfide [Gd.sub.x][Mn.sub.1 - x]S and selenide [Ti.sub.x][Mn.sub.1 - x]Se solid solutions have been identified. Their electrical and thermoelectric properties have been studied in the temperature range 80-900 K. It has been established that the substitution of [Gd.sup.2+] and [Ti.sup.2+] ions for [Mn.sup.2+] cations initiates reversal of the type of charge carrier with respect to the starting compounds MnS and MnSe. The cation substitution in solid solutions brings about a change from the hole conduction (α > 0) characteristic of the manganese monosulfide and monoselenide to the electronic conduction (α < 0).
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Structure
title Crystal structure and electrical properties of [Gd.sub.x][Mn.sub.1 - x]S and [Ti.sub.x][Mn.sub.1 - x]Se solid solutions
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