Enhanced thermal stability in [K.sub.2]O-metakaolin-based geopolymer concretes by [Al.sub.2][O.sub.3] and Si[O.sub.2] fillers addition

• Published in: Journal of materials science 2010-04, Vol.45 (7), p.1715
• Main Authors: Kamseu, E, Rizzuti, A, Leonelli, C, Perera, D
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Powders; Sintering; Toy industry
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-009-4108-1

Based on the principle of stability of geopolymer gel as refractory binder, a geopolymeric paste in the [K.sub.2]O-[Al.sub.2][O.sub.3]-Si[O.sub.2] system was developed and used to produce refractory concretes by adding various amount of α-quartz sand (grain size in the range 0.1 µm to 1 mm) and fine powder alumina (grain size in the range 0.1-100 µm). The consolidated samples were characterized before and after sintering using optical dilatometer, DSC, XRD and SEM. The total shrinkage in the range of 25-900°C was less than 3%, reduced with respect to the most diffused potassium or sodium based geopolymer systems, which generally records a >5% shrinkage. The maximum shrinkage of the basic geopolymer composition was recorded at 1000°C with a 17% shrinkage which is reduced to 12% by alumina addition. The temperature of maximum densification was shifted from 1000°C to 1150 or 1200°C by adding 75 wt% a-quartz sand or fine powder alumina respectively. The sequences of sintering of geopolymer concretes could be resumed as dehydration, dehydroxylation, densification and finally plastic deformation due to the importance of liquid phase. The geopolymer formulations developed in this study appeared as promising candidates for high-temperature applications: refractory, fire resistant or insulating materials.