Heterocyclic carbene complexes of nickel, palladium, and copper(I) as effective catalysts for the reduction of ketones

Carbene complexes of nickel, palladium, and copper(I) effectively catalyze the reduction of aromatic ketones under the influence of 2-propanol in the presence of potassium hydroxide. Bis(1,3-dimethylbenzimidazol-2-ylidene)copper(I) iodide and the polymeric complex of crown-biscarbene with copper(I)...

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Bibliographic Details
Published in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2012-03, Vol.47 (12), p.1551-1560
Main Authors: Korotkikh, N. I., Saberov, V. Sh, Kiselev, A. V., Glinyanaya, N. V., Marichev, K. A., Pekhtereva, T. M., Dudarenko, G. V., Bumagin, N. A., Shvaika, O. P.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Heterocyclic compounds
Hydrogen
Hydroxides
Ketones
Nickel
Organic Chemistry
Palladium
Palladium catalysts
Pharmacy
Polymerization
Schiff bases
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Summary:Carbene complexes of nickel, palladium, and copper(I) effectively catalyze the reduction of aromatic ketones under the influence of 2-propanol in the presence of potassium hydroxide. Bis(1,3-dimethylbenzimidazol-2-ylidene)copper(I) iodide and the polymeric complex of crown-biscarbene with copper(I) iodide show the highest catalytic efficiency.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-012-0947-9