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Size dependence of the activation energy of diffusion in multilayer Cu-Ni films

The results of studying the effect of the characteristic size on the rate of diffusion processes in nanometer Cu-Ni film systems have been reported. The film system has been prepared by sequential vacuum deposition of the components, and the activation energy of diffusion has been determined from a...

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Bibliographic Details
Published in:Physics of the solid state 2014-04, Vol.56 (4), p.823-826
Main Authors: Minenkov, A. A., Bogatyrenko, S. I., Sukhov, R. V., Kryshtal, A. P.
Format: Article
Language:English
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Summary:The results of studying the effect of the characteristic size on the rate of diffusion processes in nanometer Cu-Ni film systems have been reported. The film system has been prepared by sequential vacuum deposition of the components, and the activation energy of diffusion has been determined from a change in the electrical resistance of the film system in a heating-cooling cycle. It has been shown that the activation energy of grain-boundary diffusion decreases with decreasing characteristic size of the system and amounts to 0.25 eV for the film system with a characteristic size of 5 nm, which corresponds to an increase in the grain-boundary diffusion coefficient by 10 orders of magnitude with respect to massive samples.
ISSN:1063-7834
1090-6460
DOI:10.1134/S1063783414040210