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Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene
Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl 2 Ru(=CHPh)(PCy 3 ) 2 with...
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| Published in: | Petroleum chemistry 2012-03, Vol.52 (2), p.119-122 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c364t-4a26334540eda51770d370724b66874a79aca3b1a26c6aefc0eb0e84a74e6cd33 |
| container_end_page | 122 |
| container_issue | 2 |
| container_start_page | 119 |
| container_title | Petroleum chemistry |
| container_volume | 52 |
| creator | Bulgakov, B. A. Bermeshev, M. V. Gringol’ts, M. L. Filatova, M. P. Finkel’shtein, E. Sh |
| description | Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl
2
Ru(=CHPh)(PCy
3
)
2
with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking. |
| doi_str_mv | 10.1134/S096554411202003X |
| format | article |
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2
Ru(=CHPh)(PCy
3
)
2
with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S096554411202003X</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Carbocyclic compounds ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Crosslinked polymers ; Industrial Chemistry/Chemical Engineering</subject><ispartof>Petroleum chemistry, 2012-03, Vol.52 (2), p.119-122</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><rights>COPYRIGHT 2012 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-4a26334540eda51770d370724b66874a79aca3b1a26c6aefc0eb0e84a74e6cd33</citedby><cites>FETCH-LOGICAL-c364t-4a26334540eda51770d370724b66874a79aca3b1a26c6aefc0eb0e84a74e6cd33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Bulgakov, B. A.</creatorcontrib><creatorcontrib>Bermeshev, M. V.</creatorcontrib><creatorcontrib>Gringol’ts, M. L.</creatorcontrib><creatorcontrib>Filatova, M. P.</creatorcontrib><creatorcontrib>Finkel’shtein, E. Sh</creatorcontrib><title>Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl
2
Ru(=CHPh)(PCy
3
)
2
with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.</description><subject>Carbocyclic compounds</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crosslinked polymers</subject><subject>Industrial Chemistry/Chemical Engineering</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKs_wFuPekjNd3aPpWgVih5U8LZks7M1ZZuUZD2sv96sFTwIngbmeZ8ZZhC6pGROKRc3z6RUUgpBKSOMEP52hCZUSokV4-UxmowYj_wUnaW0JYRqKvgEPS7DPnTDDqL7NL0LfhbamcRXfXQ76N-HLrlu6K59iHWIHjzMjG9y4Ju5Jjcww7_0HJ20pktw8VOn6PXu9mV5j9dPq4flYo0tV6LHwjDFuZCCQGMk1Zo0XBPNRK1UoYXRpbGG1zTHrDLQWgI1gSIDAco2nE_R_DB3YzqonG9DH7NiTQM7Z4OH1uX-gmtV5CVlkQV6EGwMKUVoq32-0MShoqQaP1j9-WB22MFJOes3EKtt-Ig-3_WP9AVaeHMA</recordid><startdate>20120301</startdate><enddate>20120301</enddate><creator>Bulgakov, B. A.</creator><creator>Bermeshev, M. V.</creator><creator>Gringol’ts, M. L.</creator><creator>Filatova, M. P.</creator><creator>Finkel’shtein, E. Sh</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120301</creationdate><title>Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene</title><author>Bulgakov, B. A. ; Bermeshev, M. V. ; Gringol’ts, M. L. ; Filatova, M. P. ; Finkel’shtein, E. Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-4a26334540eda51770d370724b66874a79aca3b1a26c6aefc0eb0e84a74e6cd33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Carbocyclic compounds</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crosslinked polymers</topic><topic>Industrial Chemistry/Chemical Engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bulgakov, B. A.</creatorcontrib><creatorcontrib>Bermeshev, M. V.</creatorcontrib><creatorcontrib>Gringol’ts, M. L.</creatorcontrib><creatorcontrib>Filatova, M. P.</creatorcontrib><creatorcontrib>Finkel’shtein, E. Sh</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bulgakov, B. A.</au><au>Bermeshev, M. V.</au><au>Gringol’ts, M. L.</au><au>Filatova, M. P.</au><au>Finkel’shtein, E. Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2012-03-01</date><risdate>2012</risdate><volume>52</volume><issue>2</issue><spage>119</spage><epage>122</epage><pages>119-122</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl
2
Ru(=CHPh)(PCy
3
)
2
with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S096554411202003X</doi><tpages>4</tpages></addata></record> |
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| ispartof | Petroleum chemistry, 2012-03, Vol.52 (2), p.119-122 |
| issn | 0965-5441 1555-6239 |
| language | eng |
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| source | Business Source Ultimate; Springer Nature |
| subjects | Carbocyclic compounds Chemical properties Chemistry Chemistry and Materials Science Crosslinked polymers Industrial Chemistry/Chemical Engineering |
| title | Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene |
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