15,16-Epoxy-3,13(16),14-Neoclerodatrien-17,12:18,19-diolide, a new compound from Galatella punctata

The clerodane-type diterpenoid 5 S ,8 R ,9 R ,10 R ,12 S -15,16-epoxy-3,13(16),14-neoclerodatrien-17,12:18,19diolide was isolated during a chemical study of the aerial part of the terrestrial plant Galatella punctata . Its structure was elucidated using IR, PMR, and 13 C NMR spectroscopy. The crysta...

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Bibliographic Details
Published in:Chemistry of natural compounds 2013, Vol.48 (6), p.946-949
Main Authors: Adekenov, S. M., Shul’ts, E. E., Gatilov, Yu. V., Lomzov, A. A., Atazhanova, G. A., Kupriyanov, A. N.
Format: Article
Language:English
Subjects:
Crystals
Epoxy resins
Medicine
Nuclear magnetic resonance spectroscopy
Organic Chemistry
Pharmacy
Plant Sciences
Structure
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Summary:The clerodane-type diterpenoid 5 S ,8 R ,9 R ,10 R ,12 S -15,16-epoxy-3,13(16),14-neoclerodatrien-17,12:18,19diolide was isolated during a chemical study of the aerial part of the terrestrial plant Galatella punctata . Its structure was elucidated using IR, PMR, and 13 C NMR spectroscopy. The crystal and molecular structure of this diterpene was determined by an x-ray crystal structure analysis; the absolute configuration, by optical circular dichroism.
ISSN:0009-3130
1573-8388
DOI:10.1007/s10600-013-0435-1