Transformations of resins and asphaltenes during the thermal treatment of heavy oils

Changes in the properties and chemical structure of high-molecular-mass heteroatomic compounds (resins, asphaltenes) as a result of the thermal treatment of heavy oils from the Zuunbayan (Mongolia) and Usinsk (Russia) oil fields have been shown. The structural-group parameters of resins and asphalte...

Full description

Saved in:
Bibliographic Details
Published in:Petroleum chemistry 2010-03, Vol.50 (2), p.106-113
Main Authors: Dmitriev, D. E., Golovko, A. K.
Format: Article
Language:English
Subjects:
Activation energy
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Oil fields
Pyrolysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3
cites cdi_FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3
container_end_page 113
container_issue 2
container_start_page 106
container_title Petroleum chemistry
container_volume 50
creator Dmitriev, D. E.
Golovko, A. K.
description Changes in the properties and chemical structure of high-molecular-mass heteroatomic compounds (resins, asphaltenes) as a result of the thermal treatment of heavy oils from the Zuunbayan (Mongolia) and Usinsk (Russia) oil fields have been shown. The structural-group parameters of resins and asphaltenes isolated from crude oils and their thermolysis products have been determined on the basis of elemental analysis, molecular mass, and 1 H NMR data. It has been shown that the yield of gaseous, liquid, and solid products varies depending on the thermolysis time and temperature. A model for the thermal conversion of the high-molecular-mass components of petroleum is proposed and the rate constants ( k ) and activation energies ( E ) of the petroleum thermolysis reactions have been calculated. The competing routes of the conversion of petroleum components at different temperatures have been established.
doi_str_mv 10.1134/S0965544110020040
format article
fullrecord <record><control><sourceid>gale_cross</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A379570201</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A379570201</galeid><sourcerecordid>A379570201</sourcerecordid><originalsourceid>FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3</originalsourceid><addsrcrecordid>eNp9kMtqwzAQRUVpoWnaD-hOP-BUD8u2liH0BYEu6q7N2JISBVsKklLI31cm3RXKMMwwlzNwL0KPlKwo5eXTJ5GVEGVJKSGMkJJcoQUVQhQV4_IaLWa5mPVbdBfjgRBa05IvUNsGcNH4MEGy3kXsDQ462ryBUxjicQ9j0k5HrE7Buh1Oez13BkacgoY0aZdmbK_h-4y9HeM9ujEwRv3wO5fo6-W53bwV24_X9816Wwyc1amgvGpA9E0jDONkKFXTD1VTSdkI0kvKiTacgwSmFO9FXSkmRW-yKJlRiim-RKvL3x2MurPO-BRgyKX0ZAfvtLH5vua1FHVOhWaAXoAh-BiDNt0x2AnCuaOkm3Ps_uSYGXZh4nH2r0N38Kfgsq9_oB-UYXTK</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Transformations of resins and asphaltenes during the thermal treatment of heavy oils</title><source>Springer Link</source><source>BSC - Ebsco (Business Source Ultimate)</source><creator>Dmitriev, D. E. ; Golovko, A. K.</creator><creatorcontrib>Dmitriev, D. E. ; Golovko, A. K.</creatorcontrib><description>Changes in the properties and chemical structure of high-molecular-mass heteroatomic compounds (resins, asphaltenes) as a result of the thermal treatment of heavy oils from the Zuunbayan (Mongolia) and Usinsk (Russia) oil fields have been shown. The structural-group parameters of resins and asphaltenes isolated from crude oils and their thermolysis products have been determined on the basis of elemental analysis, molecular mass, and 1 H NMR data. It has been shown that the yield of gaseous, liquid, and solid products varies depending on the thermolysis time and temperature. A model for the thermal conversion of the high-molecular-mass components of petroleum is proposed and the rate constants ( k ) and activation energies ( E ) of the petroleum thermolysis reactions have been calculated. The competing routes of the conversion of petroleum components at different temperatures have been established.</description><identifier>ISSN: 0965-5441</identifier><identifier>EISSN: 1555-6239</identifier><identifier>DOI: 10.1134/S0965544110020040</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Activation energy ; Chemistry ; Chemistry and Materials Science ; Industrial Chemistry/Chemical Engineering ; Oil fields ; Pyrolysis</subject><ispartof>Petroleum chemistry, 2010-03, Vol.50 (2), p.106-113</ispartof><rights>Pleiades Publishing, Ltd. 2010</rights><rights>COPYRIGHT 2010 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3</citedby><cites>FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Dmitriev, D. E.</creatorcontrib><creatorcontrib>Golovko, A. K.</creatorcontrib><title>Transformations of resins and asphaltenes during the thermal treatment of heavy oils</title><title>Petroleum chemistry</title><addtitle>Pet. Chem</addtitle><description>Changes in the properties and chemical structure of high-molecular-mass heteroatomic compounds (resins, asphaltenes) as a result of the thermal treatment of heavy oils from the Zuunbayan (Mongolia) and Usinsk (Russia) oil fields have been shown. The structural-group parameters of resins and asphaltenes isolated from crude oils and their thermolysis products have been determined on the basis of elemental analysis, molecular mass, and 1 H NMR data. It has been shown that the yield of gaseous, liquid, and solid products varies depending on the thermolysis time and temperature. A model for the thermal conversion of the high-molecular-mass components of petroleum is proposed and the rate constants ( k ) and activation energies ( E ) of the petroleum thermolysis reactions have been calculated. The competing routes of the conversion of petroleum components at different temperatures have been established.</description><subject>Activation energy</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Oil fields</subject><subject>Pyrolysis</subject><issn>0965-5441</issn><issn>1555-6239</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kMtqwzAQRUVpoWnaD-hOP-BUD8u2liH0BYEu6q7N2JISBVsKklLI31cm3RXKMMwwlzNwL0KPlKwo5eXTJ5GVEGVJKSGMkJJcoQUVQhQV4_IaLWa5mPVbdBfjgRBa05IvUNsGcNH4MEGy3kXsDQ462ryBUxjicQ9j0k5HrE7Buh1Oez13BkacgoY0aZdmbK_h-4y9HeM9ujEwRv3wO5fo6-W53bwV24_X9816Wwyc1amgvGpA9E0jDONkKFXTD1VTSdkI0kvKiTacgwSmFO9FXSkmRW-yKJlRiim-RKvL3x2MurPO-BRgyKX0ZAfvtLH5vua1FHVOhWaAXoAh-BiDNt0x2AnCuaOkm3Ps_uSYGXZh4nH2r0N38Kfgsq9_oB-UYXTK</recordid><startdate>20100301</startdate><enddate>20100301</enddate><creator>Dmitriev, D. E.</creator><creator>Golovko, A. K.</creator><general>SP MAIK Nauka/Interperiodica</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20100301</creationdate><title>Transformations of resins and asphaltenes during the thermal treatment of heavy oils</title><author>Dmitriev, D. E. ; Golovko, A. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Activation energy</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Oil fields</topic><topic>Pyrolysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dmitriev, D. E.</creatorcontrib><creatorcontrib>Golovko, A. K.</creatorcontrib><collection>CrossRef</collection><jtitle>Petroleum chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dmitriev, D. E.</au><au>Golovko, A. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transformations of resins and asphaltenes during the thermal treatment of heavy oils</atitle><jtitle>Petroleum chemistry</jtitle><stitle>Pet. Chem</stitle><date>2010-03-01</date><risdate>2010</risdate><volume>50</volume><issue>2</issue><spage>106</spage><epage>113</epage><pages>106-113</pages><issn>0965-5441</issn><eissn>1555-6239</eissn><abstract>Changes in the properties and chemical structure of high-molecular-mass heteroatomic compounds (resins, asphaltenes) as a result of the thermal treatment of heavy oils from the Zuunbayan (Mongolia) and Usinsk (Russia) oil fields have been shown. The structural-group parameters of resins and asphaltenes isolated from crude oils and their thermolysis products have been determined on the basis of elemental analysis, molecular mass, and 1 H NMR data. It has been shown that the yield of gaseous, liquid, and solid products varies depending on the thermolysis time and temperature. A model for the thermal conversion of the high-molecular-mass components of petroleum is proposed and the rate constants ( k ) and activation energies ( E ) of the petroleum thermolysis reactions have been calculated. The competing routes of the conversion of petroleum components at different temperatures have been established.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0965544110020040</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0965-5441
ispartof Petroleum chemistry, 2010-03, Vol.50 (2), p.106-113
issn 0965-5441
1555-6239
language eng
recordid cdi_gale_infotracacademiconefile_A379570201
source Springer Link; BSC - Ebsco (Business Source Ultimate)
subjects Activation energy
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Oil fields
Pyrolysis
title Transformations of resins and asphaltenes during the thermal treatment of heavy oils
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T21%3A53%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Transformations%20of%20resins%20and%20asphaltenes%20during%20the%20thermal%20treatment%20of%20heavy%20oils&rft.jtitle=Petroleum%20chemistry&rft.au=Dmitriev,%20D.%20E.&rft.date=2010-03-01&rft.volume=50&rft.issue=2&rft.spage=106&rft.epage=113&rft.pages=106-113&rft.issn=0965-5441&rft.eissn=1555-6239&rft_id=info:doi/10.1134/S0965544110020040&rft_dat=%3Cgale_cross%3EA379570201%3C/gale_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c327t-1368a5b885f230c4d8bc68699850b9130ef33a9a2dd3b576d295bf85092fdd2d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A379570201&rfr_iscdi=true