Effect of Aggregation of Acridine Orange on the Luminescent Characteristics of Its Composites with a Zinc-Containing Coordination Polymer

It was shown that the luminescent characteristics of the composites formed by the zinc-containing coordination polymer {[Zn(L)(NDC)]·0.5H 2 O} n (L = cyclam, NDC 2– = 2,6-naphthalenedicarboxylate) with acridine orange depends on the ratio of the amounts of aggregated and isolated molecules of the dy...

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Bibliographic Details
Published in:Theoretical and experimental chemistry 2015-09, Vol.51 (4), p.259-265
Main Authors: Gurtovyi, R. I., Tsymbal, L. V., Shova, S., Lampeka, Ya. D.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Polymer industry
Polymers
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Summary:It was shown that the luminescent characteristics of the composites formed by the zinc-containing coordination polymer {[Zn(L)(NDC)]·0.5H 2 O} n (L = cyclam, NDC 2– = 2,6-naphthalenedicarboxylate) with acridine orange depends on the ratio of the amounts of aggregated and isolated molecules of the dye, which in turn depends on the conditions under which the composites are produced. In all cases energy is transferred from the coordinated polymer to the dye, leading to bimodal luminescence in the composites.
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-015-9425-7