Enthalpy increments and thermodynamic functions of rare earth samarium titanates RESmTi.sub.2O.sub.7

Enthalpy measurements have been taken on GdSmTi.sub.2O.sub.7 and DySmTi.sub.2O.sub.7 by using a high-temperature differential calorimeter at temperature between 800 and 1655 K. Thermodynamic function, such as heat capacity, entropy and Gibbs energy functions of GdSmTi.sub.2O.sub.7 and DySmTi.sub.2O....

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Published in:Journal of thermal analysis and calorimetry 2018-06, Vol.132 (3), p.1639
Main Authors: Kandan, R, Prabhakara Reddy, B, Panneerselvam, G
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Language:English
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Analysis
Thermodynamics
Titanates
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Panneerselvam, G
description Enthalpy measurements have been taken on GdSmTi.sub.2O.sub.7 and DySmTi.sub.2O.sub.7 by using a high-temperature differential calorimeter at temperature between 800 and 1655 K. Thermodynamic function, such as heat capacity, entropy and Gibbs energy functions of GdSmTi.sub.2O.sub.7 and DySmTi.sub.2O.sub.7, was derived using the data obtained in this study. The results are presented and compared with the data available in the literature. The polynomial expression of enthalpy increments obtained for GdSmTi.sub.2O.sub.7(s) and DySmTi.sub.2O.sub.7(s) in the temperature range 298-1700 K is given as: [Formula omitted]
doi_str_mv 10.1007/s10973-018-7125-y
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Thermodynamic function, such as heat capacity, entropy and Gibbs energy functions of GdSmTi.sub.2O.sub.7 and DySmTi.sub.2O.sub.7, was derived using the data obtained in this study. The results are presented and compared with the data available in the literature. 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title Enthalpy increments and thermodynamic functions of rare earth samarium titanates RESmTi.sub.2O.sub.7
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