Ultra-sensitive spectrophotometric determination of nickel after complexation and membrane filtration

• Published in: Mikrochimica acta (1966) 2012-04, Vol.177 (1-2), p.195-200
• Main Authors: Iqbal, Jibran, Yin, Changhai, Geng, Jinpei, Li, Xiaoyu, Li, Xiuyong, Du, Yiping, Liu, Bing Xiang
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Exact sciences and technology; Microengineering; Nanochemistry; Nanotechnology; Nickel; Original Paper; Spectrometric and optical methods
• ISSN: 0026-3672; 1436-5073
• DOI: 10.1007/s00604-012-0778-5

We report on a simple, sensitive and selective method for the spectrophotometric determination of Ni 2+ in water samples. The analyte ions were collected on a membrane filter in the form of their red complex with 1-(2-pyridylazo)-2-naphthol (PAN), and the absorption spectra of the colored membrane filters were acquired. Effects of pH value, sample volume, and amount of PAN were examined in order to optimize sensitivity. The interference by common other ions was eliminated using appropriate masking agents. The absorbance is linearly related to the concentration of Ni 2+ in the ranges from 0.3 to 1.5 μg L −1 , and from 2 to 10 μg L −1 , respectively, the correlation coefficients (R 2 ) being 0.9871 and 0.9954. Under the optimal conditions, the detection limit is 0.1 μg L −1 . The recoveries in case of spiked samples are between 95.0% and 101.5%, and the relative standard deviations range from 2.8% to 4.1%. Figure Direct ultra-sensitive spectrophotometric determination of Ni 2+ as Ni-PAN complex on membrane filters