New method for microextraction of ultra trace quantities of gold in real samples using ultrasound-assisted emulsification of solidified floating organic drops

• Published in: Mikrochimica acta (1966) 2011-04, Vol.173 (1-2), p.249-257
• Main Authors: Tajik, Somayeh, Taher, Mohammad Ali
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Exact sciences and technology; Microengineering; Nanochemistry; Nanotechnology; Original Paper; Spectrometric and optical methods
• ISSN: 0026-3672; 1436-5073
• DOI: 10.1007/s00604-011-0553-z

A method was developed for the determination of gold ion in water samples using microextraction based on the ultrasound-assisted emulsification of solidified floating organic drops, followed by the flame atomic absorption spectrometry. N-(4-{4-[(anilinocarbothioyl)amino]benzyl}phenyl)-N-phenylthiourea was used as chelating agent. The parameters affecting the extraction and complex formation (including the type and volume of the extracting solvent, time of sonication and centrifugation, pH, amount of the chelating agent, and sample ionic strength) were optimized. Under the optimum conditions, the calibration graph is linear in the range from 1.5 to 400 ng mL −1 , with a limit of detection of 0.45 ng mL −1 . The relative standard deviation for ten replicate determinations of gold ion in a concentration of 175 ng mL −1 was 1.7%. The procedure was successfully applied to the determination of gold in water samples, in pharmaceutical and synthetic samples, and in a standard reference material. Figa The schematic procedure of the ultrasound-assisted emulsification solidified floating organic drop microextraction is shown in above figure from A to E.