Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide

Five solvates, [[Cd[Br.sub.2](DMF)].sub.n], [[Cd[Br.sub.2](DMA)].sub.n], [[Cd[I.sub.2](DMF)].sub.n], [[Cd(DMF).sub.6]][[Cd.sub.2][I.sub.6]], and [{[Cd[(DMA).sub.6]][[[Cd.sub.5][I.sub.12]].sub.n]}.sub.m], were isolated from the ternary systems Cd[X.sub.2]-L-[H.sub.2]O (X = Br, I; L = N,N-dimethyl-ace...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of general chemistry 2018-01, Vol.88 (1), p.1
Main Authors: Bogachev, N.A, Starova, G.L, Razzhivin, A.V, Skripkin, M.Yu, Nikolskii, A.B
Format: Article
Language:English
Subjects:
Analysis
Cadmium
Dimethylformamide
Surface active agents
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 1
container_start_page 1
container_title Russian journal of general chemistry
container_volume 88
creator Bogachev, N.A
Starova, G.L
Razzhivin, A.V
Skripkin, M.Yu
Nikolskii, A.B
description Five solvates, [[Cd[Br.sub.2](DMF)].sub.n], [[Cd[Br.sub.2](DMA)].sub.n], [[Cd[I.sub.2](DMF)].sub.n], [[Cd(DMF).sub.6]][[Cd.sub.2][I.sub.6]], and [{[Cd[(DMA).sub.6]][[[Cd.sub.5][I.sub.12]].sub.n]}.sub.m], were isolated from the ternary systems Cd[X.sub.2]-L-[H.sub.2]O (X = Br, I; L = N,N-dimethyl-acetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [[Cd[(DMF).sub.6]].sup.2+] and [[[Cd.sub.2][I.sub.6]].sup.2-] ions, and the fifth solvate contains discrete [[Cd[(DMA).sub.6]].sup.2+] cations and the polymer anionic fragment [[Cd.sub.5][I.sub.12]].sup.2n-.sub.n]. Keywords: cadmium, N,N-dimethylacetamide, DMF, coordination polymers, noncovalent contacts DOI: 10.1134/S1070363218010012
doi_str_mv 10.1134/S1070363218010012
format article
fullrecord <record><control><sourceid>gale</sourceid><recordid>TN_cdi_gale_infotracacademiconefile_A725791013</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A725791013</galeid><sourcerecordid>A725791013</sourcerecordid><originalsourceid>FETCH-LOGICAL-g194t-be654e3bdd230c7f8881b4907f81028e69d095ef688fafb027d51b58918912ed3</originalsourceid><addsrcrecordid>eNpFjEtOwzAQhr0AiVI4ADtfIMWPPBx2pRSoVKmLFLbIicetkR2LxAH1cpwNh1KhGWlG33zzI3RDyYxSnt5WlBSE55xRQSghlJ2hyYiSkV2gy75_J-MhZxP0XXk71MaacMBeY5UsLThoA66kDT02Ld50O9maBstW4fnHAH7okxOLz59R7u_w62qGq9ANTRg6-HW3e-ictJHK__yFVM4MDq-8Muro3XfejfuYJQP0-MuEPX4wDsL-YGUDQbqTe6Lax-iRXqFzLW0P139zil4el9vFc7LePK0W83Wyo2UakhryLAVeK8U4aQothKB1WpK4UcIE5KUiZQY6F0JLXRNWqIzWmShpbAaKT9HsmLuTFt5Mq33oZBNLgTONb0GbyOcFy4qSEsr5D8pEe2Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide</title><source>Springer Nature</source><creator>Bogachev, N.A ; Starova, G.L ; Razzhivin, A.V ; Skripkin, M.Yu ; Nikolskii, A.B</creator><creatorcontrib>Bogachev, N.A ; Starova, G.L ; Razzhivin, A.V ; Skripkin, M.Yu ; Nikolskii, A.B</creatorcontrib><description>Five solvates, [[Cd[Br.sub.2](DMF)].sub.n], [[Cd[Br.sub.2](DMA)].sub.n], [[Cd[I.sub.2](DMF)].sub.n], [[Cd(DMF).sub.6]][[Cd.sub.2][I.sub.6]], and [{[Cd[(DMA).sub.6]][[[Cd.sub.5][I.sub.12]].sub.n]}.sub.m], were isolated from the ternary systems Cd[X.sub.2]-L-[H.sub.2]O (X = Br, I; L = N,N-dimethyl-acetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [[Cd[(DMF).sub.6]].sup.2+] and [[[Cd.sub.2][I.sub.6]].sup.2-] ions, and the fifth solvate contains discrete [[Cd[(DMA).sub.6]].sup.2+] cations and the polymer anionic fragment [[Cd.sub.5][I.sub.12]].sup.2n-.sub.n]. Keywords: cadmium, N,N-dimethylacetamide, DMF, coordination polymers, noncovalent contacts DOI: 10.1134/S1070363218010012</description><identifier>ISSN: 1070-3632</identifier><identifier>DOI: 10.1134/S1070363218010012</identifier><language>eng</language><publisher>Springer</publisher><subject>Analysis ; Cadmium ; Dimethylformamide ; Surface active agents</subject><ispartof>Russian journal of general chemistry, 2018-01, Vol.88 (1), p.1</ispartof><rights>COPYRIGHT 2018 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Bogachev, N.A</creatorcontrib><creatorcontrib>Starova, G.L</creatorcontrib><creatorcontrib>Razzhivin, A.V</creatorcontrib><creatorcontrib>Skripkin, M.Yu</creatorcontrib><creatorcontrib>Nikolskii, A.B</creatorcontrib><title>Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide</title><title>Russian journal of general chemistry</title><description>Five solvates, [[Cd[Br.sub.2](DMF)].sub.n], [[Cd[Br.sub.2](DMA)].sub.n], [[Cd[I.sub.2](DMF)].sub.n], [[Cd(DMF).sub.6]][[Cd.sub.2][I.sub.6]], and [{[Cd[(DMA).sub.6]][[[Cd.sub.5][I.sub.12]].sub.n]}.sub.m], were isolated from the ternary systems Cd[X.sub.2]-L-[H.sub.2]O (X = Br, I; L = N,N-dimethyl-acetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [[Cd[(DMF).sub.6]].sup.2+] and [[[Cd.sub.2][I.sub.6]].sup.2-] ions, and the fifth solvate contains discrete [[Cd[(DMA).sub.6]].sup.2+] cations and the polymer anionic fragment [[Cd.sub.5][I.sub.12]].sup.2n-.sub.n]. Keywords: cadmium, N,N-dimethylacetamide, DMF, coordination polymers, noncovalent contacts DOI: 10.1134/S1070363218010012</description><subject>Analysis</subject><subject>Cadmium</subject><subject>Dimethylformamide</subject><subject>Surface active agents</subject><issn>1070-3632</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFjEtOwzAQhr0AiVI4ADtfIMWPPBx2pRSoVKmLFLbIicetkR2LxAH1cpwNh1KhGWlG33zzI3RDyYxSnt5WlBSE55xRQSghlJ2hyYiSkV2gy75_J-MhZxP0XXk71MaacMBeY5UsLThoA66kDT02Ld50O9maBstW4fnHAH7okxOLz59R7u_w62qGq9ANTRg6-HW3e-ictJHK__yFVM4MDq-8Muro3XfejfuYJQP0-MuEPX4wDsL-YGUDQbqTe6Lax-iRXqFzLW0P139zil4el9vFc7LePK0W83Wyo2UakhryLAVeK8U4aQothKB1WpK4UcIE5KUiZQY6F0JLXRNWqIzWmShpbAaKT9HsmLuTFt5Mq33oZBNLgTONb0GbyOcFy4qSEsr5D8pEe2Y</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Bogachev, N.A</creator><creator>Starova, G.L</creator><creator>Razzhivin, A.V</creator><creator>Skripkin, M.Yu</creator><creator>Nikolskii, A.B</creator><general>Springer</general><scope/></search><sort><creationdate>20180101</creationdate><title>Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide</title><author>Bogachev, N.A ; Starova, G.L ; Razzhivin, A.V ; Skripkin, M.Yu ; Nikolskii, A.B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g194t-be654e3bdd230c7f8881b4907f81028e69d095ef688fafb027d51b58918912ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Analysis</topic><topic>Cadmium</topic><topic>Dimethylformamide</topic><topic>Surface active agents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bogachev, N.A</creatorcontrib><creatorcontrib>Starova, G.L</creatorcontrib><creatorcontrib>Razzhivin, A.V</creatorcontrib><creatorcontrib>Skripkin, M.Yu</creatorcontrib><creatorcontrib>Nikolskii, A.B</creatorcontrib><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bogachev, N.A</au><au>Starova, G.L</au><au>Razzhivin, A.V</au><au>Skripkin, M.Yu</au><au>Nikolskii, A.B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide</atitle><jtitle>Russian journal of general chemistry</jtitle><date>2018-01-01</date><risdate>2018</risdate><volume>88</volume><issue>1</issue><spage>1</spage><pages>1-</pages><issn>1070-3632</issn><abstract>Five solvates, [[Cd[Br.sub.2](DMF)].sub.n], [[Cd[Br.sub.2](DMA)].sub.n], [[Cd[I.sub.2](DMF)].sub.n], [[Cd(DMF).sub.6]][[Cd.sub.2][I.sub.6]], and [{[Cd[(DMA).sub.6]][[[Cd.sub.5][I.sub.12]].sub.n]}.sub.m], were isolated from the ternary systems Cd[X.sub.2]-L-[H.sub.2]O (X = Br, I; L = N,N-dimethyl-acetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [[Cd[(DMF).sub.6]].sup.2+] and [[[Cd.sub.2][I.sub.6]].sup.2-] ions, and the fifth solvate contains discrete [[Cd[(DMA).sub.6]].sup.2+] cations and the polymer anionic fragment [[Cd.sub.5][I.sub.12]].sup.2n-.sub.n]. Keywords: cadmium, N,N-dimethylacetamide, DMF, coordination polymers, noncovalent contacts DOI: 10.1134/S1070363218010012</abstract><pub>Springer</pub><doi>10.1134/S1070363218010012</doi></addata></record>
fulltext fulltext
identifier ISSN: 1070-3632
ispartof Russian journal of general chemistry, 2018-01, Vol.88 (1), p.1
issn 1070-3632
language eng
recordid cdi_gale_infotracacademiconefile_A725791013
source Springer Nature
subjects Analysis
Cadmium
Dimethylformamide
Surface active agents
title Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VI. Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T19%3A38%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solubility%20of%20d-Element%20Salts%20in%20Organic%20and%20Aqueous-Organic%20Solvents:%20VI.%20Structure%20and%20Thermal%20Stability%20of%20Cadmium%20Iodide%20and%20Bromide%20Solvates%20with%20Dimethylacetamide%20and%20Dimethylformamide&rft.jtitle=Russian%20journal%20of%20general%20chemistry&rft.au=Bogachev,%20N.A&rft.date=2018-01-01&rft.volume=88&rft.issue=1&rft.spage=1&rft.pages=1-&rft.issn=1070-3632&rft_id=info:doi/10.1134/S1070363218010012&rft_dat=%3Cgale%3EA725791013%3C/gale%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-g194t-be654e3bdd230c7f8881b4907f81028e69d095ef688fafb027d51b58918912ed3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A725791013&rfr_iscdi=true