Reaction of Benzylidene Chlorides with O-Methyl Diethylphosphinothioate

O-Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichlo...

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Bibliographic Details
Published in:Russian journal of general chemistry 2018-08, Vol.88 (8), p.1754
Main Authors: Gazizov, M.B, Valieva, G.D, Ivanova, S.Yu, Karimova, R.F, Ismagilov, R.K, Khairullin, R.A
Format: Article
Language:English
Subjects:
Chlorides
Dichloropropane
Esters
Sulfur compounds
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Summary:O-Methyl diethylphosphinothioate reacts with benzylidene chlorides to form arenecarbthioaldehyde trimers and diethylphosphinoyl chloride. This result suggests that the reaction involves initial attack of the thione sulfur atom of the phosphinothioyl group on the methine carbon atom of the gem-dichloride. Keywords: benzylidene chlorides, O-methyl diethylphosphinothioate, arenecarbthioaldehyde trimer, dechlorodiethylphosphinothioylation, dechlorodiethylphosphinothioyloxylation DOI: 10.1134/S1070363218080327
ISSN:1070-3632