Ethers and Their Oligomeric Derivatives Obtained from 2,4,6,8-Tetraglycoluril

In this work, a series of 2,4,6,8-tetra(alkoxymethyl)glycoluril esters and their derivatives was synthesized for the first time, starting from 2,4,6,8-tetra(hydroxymethyl)glycoluril, the properties and spectral data of the synthesized compounds were described. Individual oligomers, derivatives of 2,...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of general chemistry 2023-12, Vol.93 (Suppl 2), p.S456
Main Authors: Panshina, S. Yu, Ponomarenko, Ð. V, Bakibaev, A. A, Malkov, V. S, Zhortarova, A. A
Format: Article
Language:English
Subjects:
Nuclear magnetic resonance spectroscopy
Oligomers
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this work, a series of 2,4,6,8-tetra(alkoxymethyl)glycoluril esters and their derivatives was synthesized for the first time, starting from 2,4,6,8-tetra(hydroxymethyl)glycoluril, the properties and spectral data of the synthesized compounds were described. Individual oligomers, derivatives of 2,4,6,8-tetra(methoxymethyl)glycoluril, were isolated and identified, their structures were described using HPLC analysis and IR and NMR spectroscopy. A similar possibility for the dimerization/oligomerization reactions of 2,4,6,8-tetra(ethoxymethyl)-, 2,4,6,8-tetra(isopropoxymethyl)-, and 2,4,6,8-tetra(butoxymethyl) derivatives of glycoluril with the release of macrocomponents was shown.
ISSN:1070-3632
DOI:10.1134/S1070363223150069