Pd LIGAND

In the current work, we report the synthesis and characterization of new dithiocarbamate complexes derived from 1,2-benzoisothiazol-3(2H)-one (BitH). The ligand was synthesized by treating the BitH with carbon disulfide in a basic solution. The NMR technique confirmed the preparation of the ligand....

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Ethiopia 2024-04, Vol.38 (4), p.889
Main Authors: Alshdoukhi, Ibtehaj F, Al-barwari, Alyaa S.M.O, Aziz, Nazk Mohammed, Khalil, Thaaer, Faihan, Ahmed S, Al-Jibori, Subhi A, Al-Janabi, Ahmed S
Format: Article
Language:English
Subjects:
Chemical properties
Ionization
Palladium
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Summary:In the current work, we report the synthesis and characterization of new dithiocarbamate complexes derived from 1,2-benzoisothiazol-3(2H)-one (BitH). The ligand was synthesized by treating the BitH with carbon disulfide in a basic solution. The NMR technique confirmed the preparation of the ligand. The treatment of the BitdtcNa with the metal salt's solution afforded the complexes of the type [[M(Bit-dtc).sub.2]]; M = Zn, Cd, Hg, Pd, and Pt. The complexes were characterized via FT-IR and [.sup.1]H-NMR techniques. The Zn, Pd, and Pt complexes were investigated theoretically, and some of their quantum properties were determined. These parameters include HOMO-LUMO energies, electron affinity, ionization potential, chemical hardness, dipole moment and the total energies of the optimized structures. Moreover, the surface structure of Zn and Hg complexes were investigated by SEM and XRD techniques. The SEM pattern showed a cubic structures for the Zn complex while the Hg complex appeared as a nano rods structure. The calculated average particle sizes for Zn and Hg complexes were 23 and 26 nm, respectively. KEY WORDS: Dithiocarbamate, 1,2-Benzoisothiazol-3(2H)-one, DFT, SEM, XRD
ISSN:1011-3924
DOI:10.4314/bcse.v38i4.6