Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides

The study shows the possibility of photo-induced reduction of silver nitrate and formation of stable colloidal silver particles in an isopropanol-N,N-dimethylacetamide solution of titanium alkoxide (polybutyl titanate) stabilized by nitrocellulose. It is established that titanium alkoxide and the pr...

Full description

Saved in:
Bibliographic Details
Published in:Journal of applied spectroscopy 2016-07, Vol.83 (3), p.466-471
Main Authors: Kulak, A. I., Branitsky, G. A.
Format: Article
Language:English
Subjects:
Acetic acid
Analytical Chemistry
Atomic/Molecular Structure and Spectra
Backup software
Cellulose esters
Cytokinins
Explosives
Hydrolysis
Movies
Organic acids
Physics
Physics and Astronomy
Silver nitrate
Titanium dioxide
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c341t-1a612250ba353627cf27e96b70638d2b4985add66f210b67c8098d6ab389dc3c3
container_end_page 471
container_issue 3
container_start_page 466
container_title Journal of applied spectroscopy
container_volume 83
creator Kulak, A. I.
Branitsky, G. A.
description The study shows the possibility of photo-induced reduction of silver nitrate and formation of stable colloidal silver particles in an isopropanol-N,N-dimethylacetamide solution of titanium alkoxide (polybutyl titanate) stabilized by nitrocellulose. It is established that titanium alkoxide and the products of its partial hydrolysis in the liquid composition play the role of a photocatalyst for the reduction of silver ions; the introduction of nitric or acetic acid additives to the composition significantly increases its photosensitivity. The films deposited from the liquid composition, previously irradiated with visible or UV light, consist of hydrated titanium dioxide and nitrocellulose with incorporated colloidal silver. Thermal treatment of the films at 150–245°C leads to the decomposition of nitrocellulose and an increase in the absorption by silver particles.
doi_str_mv 10.1007/s10812-016-0312-3
format article
fullrecord <record><control><sourceid>gale_cross</sourceid><recordid>TN_cdi_gale_infotracmisc_A527771403</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A527771403</galeid><sourcerecordid>A527771403</sourcerecordid><originalsourceid>FETCH-LOGICAL-c341t-1a612250ba353627cf27e96b70638d2b4985add66f210b67c8098d6ab389dc3c3</originalsourceid><addsrcrecordid>eNp9kcFqGzEQhkVpIW7aB8hN0FMOm4wkr7R7NKZpAiEtsXsWWknrytVKQdKG5O0r41wMJegwYvi-gZkfoQsCVwRAXGcCHaENEN4Aqx_2AS1IK1jT8aX4iBYAlDQ9MHGGPue8B4C-o7BA5tefWKILZtbW4JuYJlVcDDiOeB29j84ojzfOP9uEXcAPrqSorfezj9niTfTzAc8VDkW54MIOb11Rwc0TXvm_8cUZm7-gT6Py2X59q-fo98337fq2uf_54269um80W5LSEMUJpS0MirWMU6FHKmzPBwGcdYYOy75rlTGcj5TAwIXu6hKGq4F1vdFMs3P07Th3p7yVLoyxJKUnl7VctVQIQZbAKnX1H6o-YyenY7Cjq_0T4fJEqEyxL2Wn5pzl3ebxlCVHVqeYc7KjfEpuUulVEpCHpOQxKVmTkoek5MGhRydXNuxskvs4p1Av9Y70D67JlQo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides</title><source>Springer Link</source><creator>Kulak, A. I. ; Branitsky, G. A.</creator><creatorcontrib>Kulak, A. I. ; Branitsky, G. A.</creatorcontrib><description>The study shows the possibility of photo-induced reduction of silver nitrate and formation of stable colloidal silver particles in an isopropanol-N,N-dimethylacetamide solution of titanium alkoxide (polybutyl titanate) stabilized by nitrocellulose. It is established that titanium alkoxide and the products of its partial hydrolysis in the liquid composition play the role of a photocatalyst for the reduction of silver ions; the introduction of nitric or acetic acid additives to the composition significantly increases its photosensitivity. The films deposited from the liquid composition, previously irradiated with visible or UV light, consist of hydrated titanium dioxide and nitrocellulose with incorporated colloidal silver. Thermal treatment of the films at 150–245°C leads to the decomposition of nitrocellulose and an increase in the absorption by silver particles.</description><identifier>ISSN: 0021-9037</identifier><identifier>EISSN: 1573-8647</identifier><identifier>DOI: 10.1007/s10812-016-0312-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acetic acid ; Analytical Chemistry ; Atomic/Molecular Structure and Spectra ; Backup software ; Cellulose esters ; Cytokinins ; Explosives ; Hydrolysis ; Movies ; Organic acids ; Physics ; Physics and Astronomy ; Silver nitrate ; Titanium dioxide</subject><ispartof>Journal of applied spectroscopy, 2016-07, Vol.83 (3), p.466-471</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>COPYRIGHT 2016 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c341t-1a612250ba353627cf27e96b70638d2b4985add66f210b67c8098d6ab389dc3c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kulak, A. I.</creatorcontrib><creatorcontrib>Branitsky, G. A.</creatorcontrib><title>Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides</title><title>Journal of applied spectroscopy</title><addtitle>J Appl Spectrosc</addtitle><description>The study shows the possibility of photo-induced reduction of silver nitrate and formation of stable colloidal silver particles in an isopropanol-N,N-dimethylacetamide solution of titanium alkoxide (polybutyl titanate) stabilized by nitrocellulose. It is established that titanium alkoxide and the products of its partial hydrolysis in the liquid composition play the role of a photocatalyst for the reduction of silver ions; the introduction of nitric or acetic acid additives to the composition significantly increases its photosensitivity. The films deposited from the liquid composition, previously irradiated with visible or UV light, consist of hydrated titanium dioxide and nitrocellulose with incorporated colloidal silver. Thermal treatment of the films at 150–245°C leads to the decomposition of nitrocellulose and an increase in the absorption by silver particles.</description><subject>Acetic acid</subject><subject>Analytical Chemistry</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Backup software</subject><subject>Cellulose esters</subject><subject>Cytokinins</subject><subject>Explosives</subject><subject>Hydrolysis</subject><subject>Movies</subject><subject>Organic acids</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Silver nitrate</subject><subject>Titanium dioxide</subject><issn>0021-9037</issn><issn>1573-8647</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kcFqGzEQhkVpIW7aB8hN0FMOm4wkr7R7NKZpAiEtsXsWWknrytVKQdKG5O0r41wMJegwYvi-gZkfoQsCVwRAXGcCHaENEN4Aqx_2AS1IK1jT8aX4iBYAlDQ9MHGGPue8B4C-o7BA5tefWKILZtbW4JuYJlVcDDiOeB29j84ojzfOP9uEXcAPrqSorfezj9niTfTzAc8VDkW54MIOb11Rwc0TXvm_8cUZm7-gT6Py2X59q-fo98337fq2uf_54269um80W5LSEMUJpS0MirWMU6FHKmzPBwGcdYYOy75rlTGcj5TAwIXu6hKGq4F1vdFMs3P07Th3p7yVLoyxJKUnl7VctVQIQZbAKnX1H6o-YyenY7Cjq_0T4fJEqEyxL2Wn5pzl3ebxlCVHVqeYc7KjfEpuUulVEpCHpOQxKVmTkoek5MGhRydXNuxskvs4p1Av9Y70D67JlQo</recordid><startdate>20160701</startdate><enddate>20160701</enddate><creator>Kulak, A. I.</creator><creator>Branitsky, G. A.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20160701</creationdate><title>Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides</title><author>Kulak, A. I. ; Branitsky, G. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c341t-1a612250ba353627cf27e96b70638d2b4985add66f210b67c8098d6ab389dc3c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acetic acid</topic><topic>Analytical Chemistry</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Backup software</topic><topic>Cellulose esters</topic><topic>Cytokinins</topic><topic>Explosives</topic><topic>Hydrolysis</topic><topic>Movies</topic><topic>Organic acids</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Silver nitrate</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kulak, A. I.</creatorcontrib><creatorcontrib>Branitsky, G. A.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of applied spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kulak, A. I.</au><au>Branitsky, G. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides</atitle><jtitle>Journal of applied spectroscopy</jtitle><stitle>J Appl Spectrosc</stitle><date>2016-07-01</date><risdate>2016</risdate><volume>83</volume><issue>3</issue><spage>466</spage><epage>471</epage><pages>466-471</pages><issn>0021-9037</issn><eissn>1573-8647</eissn><abstract>The study shows the possibility of photo-induced reduction of silver nitrate and formation of stable colloidal silver particles in an isopropanol-N,N-dimethylacetamide solution of titanium alkoxide (polybutyl titanate) stabilized by nitrocellulose. It is established that titanium alkoxide and the products of its partial hydrolysis in the liquid composition play the role of a photocatalyst for the reduction of silver ions; the introduction of nitric or acetic acid additives to the composition significantly increases its photosensitivity. The films deposited from the liquid composition, previously irradiated with visible or UV light, consist of hydrated titanium dioxide and nitrocellulose with incorporated colloidal silver. Thermal treatment of the films at 150–245°C leads to the decomposition of nitrocellulose and an increase in the absorption by silver particles.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10812-016-0312-3</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9037
ispartof Journal of applied spectroscopy, 2016-07, Vol.83 (3), p.466-471
issn 0021-9037
1573-8647
language eng
recordid cdi_gale_infotracmisc_A527771403
source Springer Link
subjects Acetic acid
Analytical Chemistry
Atomic/Molecular Structure and Spectra
Backup software
Cellulose esters
Cytokinins
Explosives
Hydrolysis
Movies
Organic acids
Physics
Physics and Astronomy
Silver nitrate
Titanium dioxide
title Photoinduced Formation of Colloidal Silver in Nitrocellulose Solutions Containing Titanium Alkoxides
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T14%3A06%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photoinduced%20Formation%20of%20Colloidal%20Silver%20in%20Nitrocellulose%20Solutions%20Containing%20Titanium%20Alkoxides&rft.jtitle=Journal%20of%20applied%20spectroscopy&rft.au=Kulak,%20A.%20I.&rft.date=2016-07-01&rft.volume=83&rft.issue=3&rft.spage=466&rft.epage=471&rft.pages=466-471&rft.issn=0021-9037&rft.eissn=1573-8647&rft_id=info:doi/10.1007/s10812-016-0312-3&rft_dat=%3Cgale_cross%3EA527771403%3C/gale_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c341t-1a612250ba353627cf27e96b70638d2b4985add66f210b67c8098d6ab389dc3c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_galeid=A527771403&rfr_iscdi=true