The role of graphene oxide in limited long-term carbonation of cement-based matrix

•Cementitious matrix with GO showed very limited long-term carbonation.•GO enhanced microstructure and reduced porosity of cementitious composite.•GO showed an interlocking effect of calcium and carbonate ions. Carbonation leads to a drop in the alkalinity of cementitious materials because carbon di...

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Bibliographic Details
Published in:Construction & building materials 2018-04, Vol.168, p.858-866
Main Authors: Mohammed, A., Sanjayan, J.G., Nazari, A., Al-Saadi, N.T.K.
Format: Article
Language:English
Subjects:
Calcium hydroxide
Carbon dioxide
Cement matrix
Cements (Building materials)
Graphene
Graphene oxide
Moisture content
Properties
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Summary:•Cementitious matrix with GO showed very limited long-term carbonation.•GO enhanced microstructure and reduced porosity of cementitious composite.•GO showed an interlocking effect of calcium and carbonate ions. Carbonation leads to a drop in the alkalinity of cementitious materials because carbon dioxide mainly attacks calcium phases and converts them into carbonated phases. The carbonation rate depends on the ease with which carbon dioxide can proceed from outer to internal surfaces. In this study, graphene oxide (GO) is used to enhance the resistance of cement matrix against carbon dioxide attack. Graphene oxide was added to cement mix sufficient amount of water to produce cementitious matrix. Visual colour change, porosity and compressive strength tests were performed to investigate effect of the carbonation on cementitious materials. The results show very low carbonation depth in the graphene oxide cement mix. After 18 months, the plain cement mixture was nearly fully carbonated compared to only about 4 mm for the GO mix. This significant result can be attributed to the influence of interlocking of GO to different anionic and cationic ions.
ISSN:0950-0618
1879-0526
DOI:10.1016/j.conbuildmat.2018.02.082