Supported Ruthenium Catalysts for Oxidation of Benzyl Alcohol under Solvent Free Conditions

The investigation comprised an evaluation of the use of the catalyst, 1%Ru/TiO2, to oxidize Phenylmethanol into benzenecarbaldehyde. nitrogen adsorption isotherms and transmittance electron microscope (TEM) were deployed to delineate the properties of the supported catalysts. The findings indicated...

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Published in:Journal of the Chemical Society of Pakistan 2022-08, Vol.44 (4), p.322-322
Main Authors: Alsaiari, Raiedhah, Rizk, Moustafa A, Musa, Esraa, Alqahtani, Huda, Alqadri, Fatima, Mohamed, Mervat, Alsaiari, Mabkhoot, Alkorbi, Ali, Shedaiwa, Iman, Alkorbi, Faeza
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Language:English
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Benzyl alcohol
Catalysts
Chemical properties
Methods
Oxidation-reduction reaction
Ruthenium
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container_title Journal of the Chemical Society of Pakistan
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creator Alsaiari, Raiedhah
Rizk, Moustafa A
Musa, Esraa
Alqahtani, Huda
Alqadri, Fatima
Mohamed, Mervat
Alsaiari, Mabkhoot
Alkorbi, Ali
Shedaiwa, Iman
Alkorbi, Faeza
description The investigation comprised an evaluation of the use of the catalyst, 1%Ru/TiO2, to oxidize Phenylmethanol into benzenecarbaldehyde. nitrogen adsorption isotherms and transmittance electron microscope (TEM) were deployed to delineate the properties of the supported catalysts. The findings indicated a superior catalytic performance from 1%Ru/TiO2 prepared using sol-immobilization method. No reaction was taken place with blank reaction or with undoped support. This was deemed to be a consequence of the dispersion and loading of Ru on the TiO2.The reaction conditions, i.e., temperature, reaction time, nature of catalyst and activating quantity, were optimized to achieve superior reaction parameters. This process gave rise to a benzyl alcohol transformation rate of up to 10%; and selectivity of benzaldehyde was 98%.
doi_str_mv 10.52568/001069/JCSP/44.04.2022
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subjects Benzyl alcohol
Catalysts
Chemical properties
Methods
Oxidation-reduction reaction
Ruthenium
title Supported Ruthenium Catalysts for Oxidation of Benzyl Alcohol under Solvent Free Conditions
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