Investigation of the effect of some polar organic solvents on the leaching and dissolution kinetics of chalcopyrite in hydrogen peroxide and sulfuric acid solution

The effect of acetic acid and ethanol as polar aqueous solvents on sulfuric acid with hydrogen peroxide as an oxidant was studied. A small amount of these polar aqueous solvents significantly improved the copper leaching recovery. The leaching parameters such as temperature, stirring speed, H2O2 con...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Ethiopia 2023-09, Vol.37 (3), p.779-788
Main Authors: Abdelraheem, Mohamed Taha Osman, Agacayak, Tevfik
Format: Article
Language:English
Subjects:
Acetic acid
Activation energy
Copper industry
Hydrogen peroxide
Investigations
Leaching
Organic acids
Sulfuric acid
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Summary:The effect of acetic acid and ethanol as polar aqueous solvents on sulfuric acid with hydrogen peroxide as an oxidant was studied. A small amount of these polar aqueous solvents significantly improved the copper leaching recovery. The leaching parameters such as temperature, stirring speed, H2O2 concentration, solid/liquid ratio, H2SO4 concentration and particle size were examined. About 76.33% as highest Cu extraction was gained with 2 M H2O2, 600 rpm stirring speed, 50 °C temperature, 1 M H2SO4, 240 min of the reaction and 75 x 53 µm particle size fraction. Further experimental tests were carried out when the stirring speed, solid-to-liquid ratio (S/L), particle size, H2O2 concentration, temperature and H2SO4 concentration were kept constant to investigate the effect of ethanol and acetic acid concentration in the range of 0–2 M. The experimental results proved that the copper extraction recovery reached to 99.03% in 180 min of the reaction with 2 M acetic acid. While 2 M of ethanol increased copper extraction recovery up to 100% in 90 min of the leaching time. The dissolution reaction found to be described by mixed kinetic model and activation energy of 54.37 kJ/mol. Addition of acetic acid and ethanol suggested reaction controlled by diffusion across product layer.   KEY WORDS: Hydrogen peroxide, Sulfuric acid, Activation energy, Leaching, Chalcopyrite   Bull. Chem. Soc. Ethiop. 2023, 37(3), 779-788.                                                             DOI: https://dx.doi.org/10.4314/bcse.v37i3.19
ISSN:1011-3924
1726-801X
DOI:10.4314/bcse.v37i3.19