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Reply to "Comment on 'Long-range electrostatic interactions between like-charged colloids: steric and confinement effects' "

In his Comment to [Phys. Rev. E 60, 6530 (1999)], Mateescu shows that while the effective interactions remain repulsive when the specific size of the microions is taken into account via a Modified Poisson-Boltzmann equation, a similar conclusion cannot be reached for the situation of complete latera...

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Published in:Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2001-10, Vol.64 (4 Pt 1), p.043401-043401
Main Authors: Trizac, E, Raimbault, J L
Format: Article
Language:English
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Summary:In his Comment to [Phys. Rev. E 60, 6530 (1999)], Mateescu shows that while the effective interactions remain repulsive when the specific size of the microions is taken into account via a Modified Poisson-Boltzmann equation, a similar conclusion cannot be reached for the situation of complete lateral confinement. This point is correct but has already been considered in a more general study [Phys. Rev. E 62, R1465 (2000), where repulsion is generically obtained]; moreover, we argue that it illustrates the irrelevancy of the notion of pair potential in completely confined configurations, as shown in a simple example.
ISSN:1539-3755
1550-2376
DOI:10.1103/PhysRevE.64.043401