Does Charge Carrier Dimensionality Increase in Mixed-Valence Salts of Tetrathiafulvalene-Terminated Dendrimers?

In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neu...

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Bibliographic Details
Published in:Organic letters 2004-06, Vol.6 (13), p.2109-2112
Main Authors: Kanibolotsky, Alexander, Roquet, Sophie, Cariou, Michel, Leriche, Philippe, Turrin, Cédric-Olivier, de Bettignies, Rémi, Caminade, Anne-Marie, Majoral, Jean-Pierre, Khodorkovsky, Vladimir, Gorgues, Alain
Format: Article
Language:English
Subjects:
Chemical Sciences
Material chemistry
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Summary:In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neutral state and cation radical, dication, and mixed-valence salts, including a closed-shell anion.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol049648x