Highly Enantioselective Synthesis of 3-Hydroxy-2-methylpropanoic Acid Esters through Ruthenium-SYNPHOS®-Catalyzed Hydrogenation: Useful Building Blocks for the Synthetic Community

Both enantiomers of 3‐hydroxy‐2‐methylpropanoic acid tert‐butyl ester were prepared with high enantioselectivity (up to 94 %) through a ruthenium‐SYNPHOS®‐promoted asymmetric hydrogenation reaction using an atom‐economic transformation from simple and inexpensive precursors.

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Published in:Advanced synthesis & catalysis 2007-07, Vol.349 (10), p.1592-1596
Main Authors: Jeulin, Séverine, Ayad, Tahar, Ratovelomanana-Vidal, Virginie, Genêt, Jean-Pierre
Format: Article
Language:English
Subjects:
asymmetric catalysis
Chemical Sciences
hydrogenation
Organic chemistry
Roche ester
ruthenium
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cited_by cdi_FETCH-LOGICAL-c3925-a6c7f854f25c7f8b1f49b7161fb4bd24a4ce7c92d5299b08675db6c50be2ef633
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creator Jeulin, Séverine
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description Both enantiomers of 3‐hydroxy‐2‐methylpropanoic acid tert‐butyl ester were prepared with high enantioselectivity (up to 94 %) through a ruthenium‐SYNPHOS®‐promoted asymmetric hydrogenation reaction using an atom‐economic transformation from simple and inexpensive precursors.
doi_str_mv 10.1002/adsc.200700025
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subjects asymmetric catalysis
Chemical Sciences
hydrogenation
Organic chemistry
Roche ester
ruthenium
title Highly Enantioselective Synthesis of 3-Hydroxy-2-methylpropanoic Acid Esters through Ruthenium-SYNPHOS®-Catalyzed Hydrogenation: Useful Building Blocks for the Synthetic Community
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