Nanostructured thermotropic PBLG–PDMS–PBLG block copolymers

We report on the nano-organization and the thermal behavior of a series of triblock copolymers composed of a central soft polydimethylsiloxane (PDMS) and two polypeptide (poly-γ-benzyl- l-glutamate) blocks. Peptide blocks with varied lengths and therefore different secondary structures (β-sheet or α...

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Bibliographic Details
Published in:Polymer (Guilford) 2007-06, Vol.48 (13), p.3717-3725
Main Authors: Ibarboure, E., Papon, E., Rodríguez-Hernández, J.
Format: Article
Language:English
Subjects:
Aminoacid polymers
Applied sciences
Chemical Sciences
Exact sciences and technology
Inorganic and organomineral polymers
Isotropization
Physicochemistry of polymers
Polymers
Preparation
Rodlike
Self-assembly
Synthetic biopolymers
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Summary:We report on the nano-organization and the thermal behavior of a series of triblock copolymers composed of a central soft polydimethylsiloxane (PDMS) and two polypeptide (poly-γ-benzyl- l-glutamate) blocks. Peptide blocks with varied lengths and therefore different secondary structures (β-sheet or α-helical) were attached to the PDMS central block. These two blocks are incompatible and microphase separate into different morphologies elucidated by polarized optical microscopy (POM), small-angle light scattering (SALS), X-ray spectroscopy (SAXS, WAXS) and atomic force microscopy (AFM). We demonstrate that the relative ratio of PBLG to PDMS direct both the type of nanodomain morphologies formed and also modifies the transition temperature. Each of these block copolymers have shown a reversible transition associated to its thermotropic liquid crystal behavior. At temperatures above the transition, the self-assembled structures are disrupted and prevented the organization at larger scales.
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2007.04.046