Electrooxidation of benzyl alcohol and benzaldehyde on a nickel oxy-hydroxide electrode in a filter-press type cell

The electrooxidation of benzyl alcohol and benzaldehyde in alkaline medium was carried out in a filter-press type cell on a nickel oxy-hydroxide electrode under different experimental conditions. An overpotential occurs in the presence of organic molecules in the solution shifting oxygen evolution t...

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Published in:Journal of applied electrochemistry 2006-09, Vol.36 (9), p.1035-1041
Main Authors: MOTHEO, A. J, TREMILIOSI-FILHO, G, GONZALEZ, E. R, KOKOH, K. B, LEGER, J.-M, LAMY, C
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Language:English
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Catalysis
Chemical Sciences
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
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cited_by cdi_FETCH-LOGICAL-c381t-e189ac561a961ab3e3af6341a1481e2794ed778ea59a7682bff6df4f4a60ae193
cites cdi_FETCH-LOGICAL-c381t-e189ac561a961ab3e3af6341a1481e2794ed778ea59a7682bff6df4f4a60ae193
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container_issue 9
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container_title Journal of applied electrochemistry
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TREMILIOSI-FILHO, G
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description The electrooxidation of benzyl alcohol and benzaldehyde in alkaline medium was carried out in a filter-press type cell on a nickel oxy-hydroxide electrode under different experimental conditions. An overpotential occurs in the presence of organic molecules in the solution shifting oxygen evolution towards higher potentials. The results obtained were conclusive that benzyl alcohol and benzaldehyde electrooxidation on NiOOH layers yielded benzoic acid as the main final reaction product. Chromatographic analysis of the bulk solution showed that the electrocatalytic oxidation of harmful molecules was carried out until the formation of acid compounds (benzoic acid) as an ultimate stage, suggesting that a Ni anode can be used successfully for waste remediation.
doi_str_mv 10.1007/s10800-006-9156-5
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subjects Catalysis
Chemical Sciences
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
title Electrooxidation of benzyl alcohol and benzaldehyde on a nickel oxy-hydroxide electrode in a filter-press type cell
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