Gold(III)-Catalyzed Nucleophilic Substitution of Propargylic Alcohols

Gold-catalyzed nucleophilic substitution on propargylic alcohols, with various C-, O-, and S-nucleophiles, is described under very mild conditions (room temperature, dichloromethane) in 0−97% yield.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2005-10, Vol.127 (41), p.14180-14181
Main Authors: Georgy, Marie, Boucard, Valérie, Campagne, Jean-Marc
Format: Article
Language:English
Subjects:
Alcohols
Alcohols - chemical synthesis
Alcohols - chemistry
Alkynes
Alkynes - chemical synthesis
Alkynes - chemistry
Catalysis
Cellular Biology
Chemical reactivity
Chemical Sciences
Chemistry
Exact sciences and technology
Gold
Gold - chemistry
Life Sciences
Molecular Structure
Organic chemistry
Propanols
Propanols - chemistry
Reactivity and mechanisms
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Description
Summary:Gold-catalyzed nucleophilic substitution on propargylic alcohols, with various C-, O-, and S-nucleophiles, is described under very mild conditions (room temperature, dichloromethane) in 0−97% yield.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0534147