A calculation of radiative lifetimes of electronically excited rovibronic levels of CuF

Radiative lifetimes for rovibronic levels of the excited valence states of CuF are calculated using a model including both spin-orbit and Coriolis interactions. According to a discussion concerning their decay mechanisms, the spin-orbit components are classified into three classes with lifetimes dif...

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Bibliographic Details
Published in:Chemical physics 1990-08, Vol.145 (1), p.101-110
Main Authors: Schamps, J., Delaval, J.M., Faucher, O.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Atomic Physics
Chemical Physics
Exact sciences and technology
Intensities and shapes of molecular spectral lines and bands
Molecular properties and interactions with photons
Physics
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Summary:Radiative lifetimes for rovibronic levels of the excited valence states of CuF are calculated using a model including both spin-orbit and Coriolis interactions. According to a discussion concerning their decay mechanisms, the spin-orbit components are classified into three classes with lifetimes differing by several orders of magnitude. Electronic transition intensity patterns are calculated and compared with spectroscopic observations.
ISSN:0301-0104
DOI:10.1016/0301-0104(90)80121-D