Cross sections and ion kinetic energy analysis for the electron impact ionization of acetylene

• Published in: The Journal of chemical physics 2006-06, Vol.124 (21), p.214307-214307-6
• Main Authors: Feil, S., Głuch, K., Bacher, A., Matt-Leubner, S., Böhme, D. K., Scheier, P., Märk, T. D.
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.2202317

Using a Nier-type electron impact ion source in combination with a double focusing two sector field mass spectrometer, partial cross sections for electron impact ionization of acetylene are measured for electron energies up to 1000 eV . Discrimination factors for ions are determined using the deflection field method in combination with a three-dimensional ion trajectory simulation of ions produced in the ion source. Analysis of the ion yield curves obtained by scanning the deflectors allows the assignment of ions with the same mass-to-charge ratio to specific production channels on the basis of their different kinetic energy distributions. This analysis also allows to determine, besides kinetic energy distributions of fragment ions, partial cross sections differential in kinetic energy. Moreover a charge separation reaction, the Coulomb explosion of the doubly charged parent ions C 2 H 2 + + into the fragment ions C 2 H + and H + , is investigated and its mean kinetic energy release ( ⟨ KER ⟩ = 3.88 eV ) is deduced.