Water and oil wettability of hybrid organic–inorganic titanate–silicate thin films deposited via a sol–gel route

• Published in: Surface science 2009-09, Vol.603 (17), p.2698-2707
• Main Authors: Houmard, M., Vasconcelos, D.C.L., Vasconcelos, W.L., Berthomé, G., Joud, J.C., Langlet, M.
• Format: Article
• Language: English
• Subjects: Chemical Sciences; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Engineering Sciences; Exact sciences and technology; Material chemistry; Materials; Oil wettability; Organic–inorganic hybrids; Physics; Sol–gel process; Thin films; Water wettability
• ISSN: 0039-6028; 1879-2758
• DOI: 10.1016/j.susc.2009.07.005

Hybrid organic–inorganic titanate–silicate thin films were deposited on silicium wafer via a sol–gel route. Hybrid sols were formulated by mixing an inorganic titanium alkoxide solution with solutions of hybrid organic–inorganic silicon alkoxides partially substituted with non-hydrolysable alkyl chains. Three organo-silicate precursors were used to introduce methyl, octyl, or hexadecyl chains in the oxide network. Physico-chemical and morphological properties of derived hybrid films have been studied by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, ellipsometry, and atomic force microscopy. Contact angle measurements have also been performed to assess the water and mineral oil wettability of hybrid films. Wettability properties of these films are discussed with respect to physico-chemical and morphological features. It is shown that increasing the fraction and length of alkyl chains in the oxide network conjointly increases water and oil contact angles measured on such hybrid films.