Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling

Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins. A 2D metal−organic network formed via PO···Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivative...

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Bibliographic Details
Published in:Organic letters 2009-09, Vol.11 (17), p.3842-3845
Main Authors: Enakieva, Yulia Y, Bessmertnykh, Alla G, Gorbunova, Yulia G, Stern, Christine, Rousselin, Yoann, Tsivadze, Aslan Y, Guilard, Roger
Format: Article
Language:English
Subjects:
Catalysis
Chemical Sciences
Coordination chemistry
Metalloporphyrins - chemical synthesis
Metalloporphyrins - chemistry
Molecular Structure
Other
Palladium - chemistry
Zinc - chemistry
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Summary:Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins. A 2D metal−organic network formed via PO···Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivatives.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol901421e