Surface esterification of cellulose fibres: Processing and characterisation of low-density polyethylene/cellulose fibres composites

• Published in: Composites science and technology 2008, Vol.68 (1), p.193-201
• Main Authors: Pasquini, Daniel, Teixeira, Eliangela de Morais, Curvelo, Antonio Aprigio da Silva, Belgacem, Mohamed Naceur, Dufresne, Alain
• Format: Article
• Language: English
• Subjects: A. Cellulose fibres; A. Coupling agents; A. Wood; Applied sciences; B. Interface; Chemical and Process Engineering; Composites; Engineering Sciences; Exact sciences and technology; Forms of application and semi-finished materials; Polymer industry, paints, wood; Technology of polymers
• ISSN: 0266-3538; 1879-1050
• DOI: 10.1016/j.compscitech.2007.05.009

Low-density polyethylene was filled with cellulose fibres from sugar cane bagasse obtained from organosolv/supercritical carbon dioxide pulping process. The fibres were also used after chemical modification with octadecanoyl and dodecanoyl chloride acids. The morphology, thermal properties, mechanical properties in both the linear and nonlinear range, and the water absorption behaviour of ensuing composites were tested. The evidence of occurrence of the chemical modification was checked by X-ray photoelectron spectrometry. The degree of polymerisation of the fibres and their intrinsic properties (zero tensile strength) were determined. It clearly appeared that the surface chemical modification of cellulose fibres resulted in improved interfacial adhesion with the matrix and higher dispersion level. However, composites did not show improved mechanical performances when compared to unmodified fibres. This surprising result was ascribed to the strong lowering of the degree of polymerisation of cellulose fibres (as confirmed by the drastic decrease of their zero tensile strength) after chemical treatment despite the mild conditions used.