Tuning the shape of nanoparticles to control their catalytic properties : selective hydrogenation of 1,3-butadiene on Pd/Al2O3

Shape-controlled Pd nanoparticles supported on powder alumina are more efficient for selective butadiene hydrogenation to butene when they exhibit high fractions of (111) facets.

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2008, Vol.10 (36), p.5504-5506
Main Authors: PICCOLO, Laurent, VALCARCEL, Ana, BAUSACH, Marta, THOMAZEAU, Cécile, UZIO, Denis, BERHAULT, Gilles
Format: Article
Language:English
Subjects:
Alkenes - chemical synthesis
Alkenes - chemistry
Aluminum Oxide - chemistry
Butadienes - chemistry
Catalysis
Chemical Sciences
Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Hydrogenation
Metal Nanoparticles - chemistry
Palladium - chemistry
Particle Size
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Time Factors
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Description
Summary:Shape-controlled Pd nanoparticles supported on powder alumina are more efficient for selective butadiene hydrogenation to butene when they exhibit high fractions of (111) facets.
ISSN:1463-9076
1463-9084
DOI:10.1039/b809651a