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Temporal and spatial monitoring of mobile nanoparticles in a vineyard soil: evidence of nanoaggregate formation

Mechanisms of formation, stabilization, liberation, transport and deposition of nanoparticles and their relationship to contaminant transport remain scarcely investigated in natural porous media. This study investigated nanoparticles mobilized in the pore space of a French vineyard soil by observing...

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Bibliographic Details
Published in:European journal of soil science 2010-08, Vol.61 (4), p.456-468
Main Authors: Perdrial, N, Perdrial, J.N, Delphin, J.-E, Elsass, F, Liewig, N
Format: Article
Language:English
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Summary:Mechanisms of formation, stabilization, liberation, transport and deposition of nanoparticles and their relationship to contaminant transport remain scarcely investigated in natural porous media. This study investigated nanoparticles mobilized in the pore space of a French vineyard soil by observing mobile soil-derived organic matter (SOM) and minerals in pore fluids over an 8-month monitoring period. Samples were collected in situ and investigated by transmission electron microscopy coupled to electron-dispersive spectroscopy. The main types of nanoparticles transported within the soil were clay, bacteria, SOM and nanoaggregates. Nanometric clay particles were enriched in various metals (Fe, Zn, As and Pb) and organically-derived constituents. Analyses of bacteria showed enrichments in Pb. SOM consisted of small carbon-based particles (
ISSN:1351-0754
1365-2389
DOI:10.1111/j.1365-2389.2010.01263.x