Heterocomplementary H-Bonding RAFT Agents as Tools for the Preparation of Supramolecular Miktoarm Star Copolymers

Supramolecular miktoarm stars (AB2 type) composed of poly (methyl methacrylate)-polystyrene2 (PMMA-PS2), poly(isoprene)-polystyrene2 (PI-PS2), and poly(vinyl acetate)-polystyrene2 (PVAc-PS2) were successfully synthesized by assembling reversible addition−fragmentation chain transfer (RAFT)-polymeriz...

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Published in:International journal of biological macromolecules 2010-07, Vol.43 (14), p.5981-5988
Main Authors: Chen, Senbin, Bertrand, Arthur, Chang, Xijun, Alcouffe, Pierre, Ladavière, Catherine, Gérard, Jean-François, Lortie, Frédéric, Bernard, Julien
Format: Article
Language:English
Subjects:
Applied sciences
Chemical Sciences
Exact sciences and technology
Material chemistry
Organic polymers
Physicochemistry of polymers
Polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-a389t-2603176622d268cb79e17683ff56cb3c036e30d5e1c0f1436eca613285a997263
cites cdi_FETCH-LOGICAL-a389t-2603176622d268cb79e17683ff56cb3c036e30d5e1c0f1436eca613285a997263
container_end_page 5988
container_issue 14
container_start_page 5981
container_title International journal of biological macromolecules
container_volume 43
creator Chen, Senbin
Bertrand, Arthur
Chang, Xijun
Alcouffe, Pierre
Ladavière, Catherine
Gérard, Jean-François
Lortie, Frédéric
Bernard, Julien
description Supramolecular miktoarm stars (AB2 type) composed of poly (methyl methacrylate)-polystyrene2 (PMMA-PS2), poly(isoprene)-polystyrene2 (PI-PS2), and poly(vinyl acetate)-polystyrene2 (PVAc-PS2) were successfully synthesized by assembling reversible addition−fragmentation chain transfer (RAFT)-polymerized chains bearing hydrogen-bonding heterocomplementary associating units. To this end, thymine and diaminopyridine-functionalized chain transfer agents were designed to efficiently mediate the polymerization of vinyl acetate, methyl methacrylate, isoprene, and styrene. The selective associations of the resulting hydrogen-bonding macromolecular building blocks PVAc/PS, PI/PS, and PMMA/PS were demonstrated by 1H NMR in CDCl3 solutions. Miktoarm stars formation in the bulk was also confirmed by transmission electronic microscopy.
doi_str_mv 10.1021/ma101044y
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source ScienceDirect Freedom Collection; American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Chemical Sciences
Exact sciences and technology
Material chemistry
Organic polymers
Physicochemistry of polymers
Polymers
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Heterocomplementary H-Bonding RAFT Agents as Tools for the Preparation of Supramolecular Miktoarm Star Copolymers
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